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使用椰子果冻粉改善竹芋淀粉和海藻酸钠成膜性能的生物复合膜的表征

Characterization of a biocomposite film using coconut jelly powder to improve arrowroot starch and sodium alginate film forming properties.

作者信息

Charles Albert Linton, Nero Zoannie, Sulmartiwi Laksmi, Triningtyas Putranti Hikmah, Putra Nanda Rizki, Abdillah Annur Ahadi, Alamsjah Mochammad Amin

机构信息

Department of Tropical Agriculture and International Cooperation, National Pingtung University of Science and Technology,1 Shuefu Road, Neipu, Pingtung 91201, Taiwan.

Department of Tropical Agriculture and International Cooperation, National Pingtung University of Science and Technology,1 Shuefu Road, Neipu, Pingtung 91201, Taiwan.

出版信息

Int J Biol Macromol. 2025 Mar;292:139161. doi: 10.1016/j.ijbiomac.2024.139161. Epub 2024 Dec 25.

Abstract

Composite polymers are promising solution to structural setbacks of starch and alginate-based films due to their hydrophilic attributes. Hence, this study aimed to investigate young coconut jelly powder (CJP), an under-utilized by-waste, as a filler using the casting method to develop a novel biocomposite from increments of CJP (1-3 %) to a blended resin of arrowroot starch, sodium alginate, and glycerol. Moreover, the films were characterized by physicomechanical (visual aspect, thickness, color, moisture content, tensile strength, and elongation at break); surface microstructure; water barrier (water vapor permeability, water solubility, and water activities); thermal, crystallinity, and functional group properties; soil, river water, and seawater biodegradability; and coating application in cherry tomato. The results showed CJP improved tensile strength from 1.84 to 9.35 MPa and lowered moisture content from 33.44 to 18.92 %, and revealed compatibility within a semi-crystalline film matrix of high thermal stability, which depicted smooth surface areas and opacity suitable for packaging. The findings demonstrated faster biodegradability rates in soils (14-35 days) than water tests (152-180 days). Furthermore, coating significantly delayed weight loss while preserving visible color and flesh quality of the cherry tomato. In conclusion, the CJP-based biocomposite films presented a potential biodegradable eco-friendly alternative to the food packaging industry.

摘要

由于其亲水性,复合聚合物有望解决基于淀粉和藻酸盐的薄膜的结构缺陷。因此,本研究旨在研究未充分利用的废弃原料——嫩椰子果冻粉(CJP),采用流延法将其作为填料,通过增加CJP(1%-3%)至竹芋淀粉、海藻酸钠和甘油的混合树脂中,来开发一种新型生物复合材料。此外,对薄膜进行了物理机械性能(外观、厚度、颜色、水分含量、拉伸强度和断裂伸长率)、表面微观结构、阻水性能(水蒸气透过率、水溶性和水分活度)、热性能、结晶度和官能团性质、在土壤、河水和海水中的生物降解性以及在樱桃番茄上的包衣应用等方面的表征。结果表明,CJP使拉伸强度从1.84 MPa提高到9.35 MPa,水分含量从33.44%降低到18.92%,并显示出在高热稳定性的半结晶薄膜基质中的相容性,该基质具有适合包装的光滑表面区域和不透明度。研究结果表明,在土壤中的生物降解速度(14 - 35天)比在水中的测试速度(152 - 180天)更快。此外,包衣显著延迟了樱桃番茄的重量损失,同时保持了其可见颜色和果肉品质。总之,基于CJP的生物复合薄膜为食品包装行业提供了一种潜在的可生物降解的环保替代品。

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