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罗丹明B作为热致变色传感器在评估低温涂料性能中的应用。

Application of rhodamine B as thermochromic sensor for evaluation of performance of cold paint.

作者信息

Golshan Marzieh, Mohammadzadeh Fatemeh, Haddadi-Asl Vahid, Salami-Kalajahi Mehdi

机构信息

Faculty of Polymer Engineering, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, Iran.

Institute of Polymeric Materials, Sahand University of Technology, P.O. Box 51335-1996, Tabriz, Iran.

出版信息

Sci Rep. 2024 Dec 28;14(1):31443. doi: 10.1038/s41598-024-83173-1.

Abstract

A thermochromic pigment, derived from reaction of ethylenediamine and rhodamine B known as MA-RB, has been successfully developed. This pigment showcases temperature-controlled visible color-transformation properties in both solid and solution states. The thermochromic pigment MA-RB exhibits a notable color change from light pink to rose red, triggered by thermal excitation. In its solid form, MA-RB also displays thermochromic behavior, shifting its color from pink to rose red when exposed to visible light. MA-RB distinct thermochromic properties, characterized by visible color changes, make it a promising material for applications in both solid and liquid systems. Its ability to respond to temperature changes makes it an attractive option for coatings, offering a non-intrusive alternative for temperature measurement. It is successfully applied to measure the performance of cold paint which contains coumarin derivate as cold pigment. This can open a new filed in application of thermochromic pigments in energy systems such as smart windows, wearable fabrics, etc. or in measurement devices of temperature.

摘要

一种由乙二胺和罗丹明B反应得到的热致变色颜料MA-RB已成功研发出来。这种颜料在固态和溶液状态下均展现出温度可控的可见颜色转变特性。热致变色颜料MA-RB在热激发下会出现从浅粉色到玫瑰红的显著颜色变化。在固态时,MA-RB也表现出热致变色行为,在可见光照射下颜色从粉色转变为玫瑰红。MA-RB独特的热致变色特性,以可见颜色变化为特征,使其成为固态和液体系统应用中有前景的材料。它对温度变化的响应能力使其成为涂料的一个有吸引力的选择,为温度测量提供了一种非侵入性的替代方法。它已成功应用于测量含有香豆素衍生物作为冷颜料的冷漆的性能。这可以在热致变色颜料于智能窗户、可穿戴织物等能源系统或温度测量设备中的应用方面开辟一个新领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84cb/11682077/c76ff1bd680c/41598_2024_83173_Fig1_HTML.jpg

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