Nikhar Shibyendu, Chakraborty Mitun
University Institute of Biotechnology, Chandigarh University (Gharuan), NH-5, Ludhiana-Chandigarh State Highway, Punjab 140413, India.
Department of Biotechnology, Parul Institute of Technology, Vadodara, Gujarat¸ India E-mail:
Water Sci Technol. 2024 Dec;90(12):3193-3209. doi: 10.2166/wst.2024.385. Epub 2024 Nov 25.
In this study, three different materials were investigated for their ability to degrade benzene, toluene, and xylene (BTX) using light energy. The materials studied were activated charcoal (AC), zeolitic imidazolate framework (ZIF-8), and zirconium metal-organic framework (Zr-MOF). Initially, AC, ZIF-8, and Zr-MOF were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area analysis, and spectroscopic analysis techniques. Based on their excellent features, that is, band gap (5.5, 5.45, and 4.75 eV), surface area (711.5, 1,122.1, and 535.4 m/g), and pore volume (0.291, 0.369, and 0.628 cm/g), a comparative photodegradation analysis of BTX was performed in acetonitrile. We found that Zr-MOF is the best photocatalyst to degrade BTX, with degradation percentages of 97, 95, and 94% (B > T > X), respectively, followed by ZIF-8 and AC. Our study suggests that these photocatalysts can be used to degrade BTX using light energy, which could reduce the health and environmental impacts of BTX. Our results illustrate that advanced porous materials may be established as photocatalyst materials with the potential to address the long-standing challenges associated with pollutant degradation.
在本研究中,研究了三种不同材料利用光能降解苯、甲苯和二甲苯(BTX)的能力。所研究的材料为活性炭(AC)、沸石咪唑酯骨架材料(ZIF-8)和锆基金属有机骨架材料(Zr-MOF)。最初,使用X射线衍射(XRD)、傅里叶变换红外(FTIR)光谱、扫描电子显微镜(SEM)、布鲁诺尔-埃米特-泰勒(BET)表面积分析和光谱分析技术对AC、ZIF-8和Zr-MOF进行了表征。基于它们的优异特性,即带隙(5.5、5.45和4.75电子伏特)、表面积(711.5、1122.1和535.4平方米/克)和孔体积(0.291、0.369和0.628立方厘米/克),在乙腈中对BTX进行了比较光降解分析。我们发现Zr-MOF是降解BTX的最佳光催化剂,降解率分别为97%、95%和94%(B>T>X),其次是ZIF-8和AC。我们的研究表明,这些光催化剂可用于利用光能降解BTX,这可以减少BTX对健康和环境的影响。我们的结果表明,先进的多孔材料有望成为具有解决与污染物降解相关长期挑战潜力的光催化剂材料。