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基于OSA改性淀粉的皮克林乳液的特性及其在肌原纤维蛋白凝胶中的应用。

Characteristics of OSA modified starch-based Pickering emulsion and its application to myofibrillar protein gel.

作者信息

Wu Mangang, Xu Yuyu, Gu Chen, Wang Jiahao, Wang Qingling, Yin Peipei, Zhu Tianhao, Yin Qing, Zhao Xinxin, Jin Duxin, Liu Rui, Ge Qingfeng, Yu Hai

机构信息

College of Food Science and Engineering, Yangzhou University, Yangzhou, China.

出版信息

J Sci Food Agric. 2025 Apr;105(6):3397-3405. doi: 10.1002/jsfa.14101. Epub 2024 Dec 29.

Abstract

BACKGROUND

Pickering emulsions prepared with octenyl succinic anhydride-modified starch (OSAS) show significant promise as replacements for animal fat. However, the underlying mechanism of incorporating an OSAS-based Pickering emulsion into a myofibrillar protein (MP) gel and its impact on the gel properties remain poorly understood. In this study, the effects of OSAS at varying concentrations (0-10.0 g kg) on the stability of Pickering emulsion and the resultant gel properties of MP were investigated.

RESULTS

Emulsion stability was assessed using a stability analyzer, revealing a significant enhancement with increasing OSAS concentration. Compared with MP gel, the incorporation of the OSAS-based Pickering emulsion markedly improved the texture of the composite gels, increasing the gel hardness from 0.28 to 0.66 N. Moreover, water-holding capacity of composite gels rose from 28.5% to 61.2%, with a notable increase in immobilized water and a decrease in mobilized water. Rheological analysis revealed that the interactions of modified starch with MP and water molecules bolstered the elastic modulus of the gels. Additionally, the presence of OSAS-stabilized emulsions led to reduced surface hydrophobicity and sulfhydryl content of proteins in the gels, while partially inhibiting protein oxidation.

CONCLUSION

OSAS, notably at a high concentration, improved the physical stability of Pickering emulsion and the properties of MP gel. This research provides fundamental insights for the development of high-quality emulsified meat products. © 2024 Society of Chemical Industry.

摘要

背景

用辛烯基琥珀酸酐改性淀粉(OSAS)制备的Pickering乳液作为动物脂肪的替代品显示出巨大潜力。然而,将基于OSAS的Pickering乳液加入肌原纤维蛋白(MP)凝胶的潜在机制及其对凝胶特性的影响仍知之甚少。在本研究中,研究了不同浓度(0 - 10.0 g/kg)的OSAS对Pickering乳液稳定性以及MP所得凝胶特性的影响。

结果

使用稳定性分析仪评估乳液稳定性,结果表明随着OSAS浓度的增加稳定性显著增强。与MP凝胶相比,加入基于OSAS的Pickering乳液显著改善了复合凝胶的质地,使凝胶硬度从0.28 N增加到0.66 N。此外,复合凝胶的持水能力从28.5%提高到61.2%,固定水显著增加,游离水减少。流变学分析表明,改性淀粉与MP和水分子的相互作用增强了凝胶的弹性模量。此外,OSAS稳定乳液的存在导致凝胶中蛋白质的表面疏水性和巯基含量降低,同时部分抑制了蛋白质氧化。

结论

OSAS,尤其是高浓度时,改善了Pickering乳液的物理稳定性和MP凝胶的特性。本研究为开发高品质乳化肉制品提供了基础见解。© 2024化学工业协会。

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