Humidity-Sensing and Moisture-Steering Liquid Crystal Elastomer Actuator.

A liquid crystal elastomer (LCE) actuator capable of colorimetric humidity sensing is realized. The designed LCE features acid protonated amino azobenzene side groups in its structure, which endow the actuator with the hygroscopicity and act as the humidity reporter via color changes. Given that the protonated and deprotonated chromophore absorb visible light at different wavelengths, when the protonated LCE is under higher humidity, it absorbs more water that deprotonates azobenzene and leads to a change in color. This humidity-dependent color change is fast, because surface protonation of the actuator is enough. The initial color and the sensitivity to humidity variation are determined by the extent of acid protonation, and the reversible color changes are distinguishable by the naked eye over a wide humidity range. The humidity sensing of LCE actuator in motion is demonstrated using thermally driven rolling rod actuators. Moreover, through spatial-selective exposure of the rolling rod actuator to water mist, the moisture can act as a stimulus to change or reverse the rolling direction and reduce the rolling speed. The achieved nature-inspired colorimetric humidity sensing capability represents an intelligent function for LCE actuators and may widen their application scope.