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海藻酸钠在盐溶液中减阻性能的实验研究

Experimental study on the drag reduction performance of sodium alginate in saline solutions.

作者信息

Cheng Zhensong, Zhang Xin, Dai Xiaodong, Zhai Hengli, Song Xinwang, Wang Xudong, Gao Liang, Zhang Guoxin, Lu Yuan, Li Lei, Yan Xiu, Zhang Jianhua

机构信息

College of Petroleum Engineering, Shandong Institute of Petroleum and Chemical Technology, Dongying, 257061, Shandong, People's Republic of China.

Downhole Service of SINOPEC Shengli Oilfield Service Corporation, Dongying, People's Republic of China.

出版信息

Sci Rep. 2024 Dec 30;14(1):32123. doi: 10.1038/s41598-024-83910-6.

DOI:10.1038/s41598-024-83910-6
PMID:39739014
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11685985/
Abstract

Since the discovery of the turbulence drag reduction phenomenon over 70 years ago, it has been recognized that the addition of small quantities of drag-reducing agents to fluids can significantly decrease wall shear stress, thereby enhancing fluid pumpability. In many applications, the fluids often contain salts, such as those used in fracturing processes within the petroleum sector. The aim of this study is to experimentally investigate the effects of salinity, flow rate, and polymer concentration on the drag reduction performance of sodium alginate in circular pipes. The experimental process was designed using Response Surface Methodology (RSM), and a predictive regression model for the drag reduction rate (DR) was developed. By comparing the predicted results with the experimental outcomes, we found that the accuracy of the predictive model is high, with the error controlled within ± 20%. To provide a more intuitive understanding of the effect of salinity on the drag reduction performance of sodium alginate, this paper introduces the innovative concept of Drag Reduction Inhibition Rate (ε). The results indicate that the drag reduction rate in saline solutions is generally lower than that in salt-free solutions. However, during the initial stage of turbulence, a small amount of salt facilitates the unfolding of sodium alginate molecules, thereby enhancing the drag reduction effect (ε > 100%). Following this initial turbulent phase, the inhibitory effect of salinity on the polymer becomes pronounced, causing the drag reduction inhibition rate to decrease from 115 to 20%. We propose that high concentrations of salt may restrict the extent of polymer unfolding, resulting in concentrated solutions degrading into dilute solutions.

摘要

自70多年前发现湍流减阻现象以来,人们已经认识到向流体中添加少量减阻剂可以显著降低壁面剪应力,从而提高流体的泵送能力。在许多应用中,流体通常含有盐分,例如石油行业压裂过程中使用的那些盐分。本研究的目的是通过实验研究盐度、流速和聚合物浓度对圆形管道中藻酸钠减阻性能的影响。实验过程采用响应面法(RSM)进行设计,并建立了减阻率(DR)的预测回归模型。通过将预测结果与实验结果进行比较,我们发现预测模型的准确性很高,误差控制在±20%以内。为了更直观地理解盐度对藻酸钠减阻性能的影响,本文引入了减阻抑制率(ε)这一创新概念。结果表明,盐溶液中的减阻率通常低于无盐溶液中的减阻率。然而,在湍流初始阶段,少量盐有助于藻酸钠分子展开,从而增强减阻效果(ε>100%)。在这个初始湍流阶段之后,盐度对聚合物的抑制作用变得明显,导致减阻抑制率从115%降至20%。我们认为高浓度的盐可能会限制聚合物展开的程度,导致浓溶液降解为稀溶液。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/d5207d195ea9/41598_2024_83910_Fig9_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/a9d92b730a42/41598_2024_83910_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/d5207d195ea9/41598_2024_83910_Fig9_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/5f0b0793bfc5/41598_2024_83910_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/dae69fb20ad9/41598_2024_83910_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/a395fe66c102/41598_2024_83910_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/91777702dd14/41598_2024_83910_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/cfb1a3e1be1d/41598_2024_83910_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/34812161364b/41598_2024_83910_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/3e12a29e19b0/41598_2024_83910_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/a9d92b730a42/41598_2024_83910_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2dfa/11685985/d5207d195ea9/41598_2024_83910_Fig9_HTML.jpg

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