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由熔纺原生沥青质制成的碳纤维的物理化学性质

Physicochemical Properties of Carbon Fiber Formulated from Melt-Spun Raw Asphaltene.

作者信息

Khodaei Booran Shahrad, Chen Jiawei, Islam Md Minhajul, Ekaette Idaresit, Ngo TriDung, McDermott Mark, Tang Tian, Ayranci Cagri

机构信息

Department of Mechanical Engineering, University of Alberta, 116 St & 85 Avenue, Edmonton, Alberta T6G 2R3, Canada.

Department of Chemistry, University of Alberta, 116 St & 85 Avenue, Edmonton, Alberta T6G 2R3, Canada.

出版信息

ACS Omega. 2024 Dec 11;9(51):50318-50325. doi: 10.1021/acsomega.4c06464. eCollection 2024 Dec 24.

DOI:10.1021/acsomega.4c06464
PMID:39741853
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11683617/
Abstract

One of the challenges in carbon fiber production centers around the high cost of raw materials required for fiber precursors or complex production processes involving multiple steps. This research paper delves into the utilization of asphaltene sourced from Alberta oil sands as an alternative precursor material that is low cost for carbon fiber production. We investigated the carbon fiber production process using a blend of different asphaltene types via melt-spinning technology. Carbon fibers produced from asphaltene-based precursors exhibit an average diameter of 12.66 ± 3.06 μm, an ultimate tensile strength (UTS) of 524.07 ± 218.53 MPa, an elastic modulus of 34.68 ± 15.61 GPa, and a strain at the UTS of 2.48 ± 0.97%. The results validate the viability of asphaltene as a precursor fiber and highlight the potential of carbon fibers.

摘要

碳纤维生产面临的挑战之一在于纤维前驱体所需原材料成本高昂,或涉及多步骤的复杂生产过程。本研究论文深入探讨了将源自阿尔伯塔油砂的沥青质用作碳纤维生产低成本替代前驱体材料的情况。我们通过熔融纺丝技术,使用不同类型沥青质的混合物研究了碳纤维生产过程。由沥青质基前驱体制备的碳纤维平均直径为12.66±3.06μm,极限抗拉强度(UTS)为524.07±218.53MPa,弹性模量为34.68±15.61GPa,UTS处的应变为2.48±0.97%。结果验证了沥青质作为前驱体纤维的可行性,并突出了碳纤维的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/4010ea1a812b/ao4c06464_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/b00a401e4c66/ao4c06464_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/72f79a6edaec/ao4c06464_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/d73b6de1bb44/ao4c06464_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/422b45a30e8c/ao4c06464_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/4010ea1a812b/ao4c06464_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/b00a401e4c66/ao4c06464_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/72f79a6edaec/ao4c06464_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/d73b6de1bb44/ao4c06464_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/422b45a30e8c/ao4c06464_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fe98/11683617/4010ea1a812b/ao4c06464_0005.jpg

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本文引用的文献

1
Toward molecular characterization of asphaltene from different origins under different conditions by means of FT-IR spectroscopy.通过傅里叶变换红外光谱法对不同来源、不同条件下的沥青质进行分子表征。
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Physicochemical Properties of Poly-Vinyl Polymers and Their Influence on Ketoprofen Amorphous Solid Dispersion Performance: A Polymer Selection Case Study.聚乙烯基聚合物的物理化学性质及其对酮洛芬无定形固体分散体性能的影响:一个聚合物选择的案例研究
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Time Dependent Structure and Property Evolution in Fibres during Continuous Carbon Fibre Manufacturing.
连续碳纤维制造过程中纤维随时间的结构与性能演变
Materials (Basel). 2019 Apr 1;12(7):1069. doi: 10.3390/ma12071069.
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Graphene nanoribbons as an advanced precursor for making carbon fiber.石墨烯纳米带作为制造碳纤维的先进前体。
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