基于碳二磷烯配体的碳中心反应性，实现氧化还原非无辜配体/配体双键活化。
Carbon-Centered Reactivity in Carbodiphosphorane-Based Ligands Allowing for Redox-Non-Innocent Ligand/Ligand Dual Bond-Activation.
作者信息
Schatz Philipp, Xu Weiqin, Rynek Sebastian, Maser Leon, Heise Niels, Fuhr Olaf, Fenske Dieter, Haeri Haleh Hashemi, Hinderberger Dariush, Vogt Matthias, Langer Robert
机构信息
Institute of Chemistry, Faculty of Natural Science II, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120, Halle(Saale), Germany.
Chemistry Department, Guangdong University of Education, Guangzhou, 510303, PR China.
出版信息
Angew Chem Int Ed Engl. 2025 Feb 10;64(7):e202419786. doi: 10.1002/anie.202419786. Epub 2025 Jan 21.
A pronounced nucleophilicity in combination with a distinct redox non-innocence is a unique feature of a coordinated ligand, which in the current case, leads to unprecedented carbon-centered reactivity patterns: A carbodiphosphorane-based (CDP) pincer-type rhodium complex allows to cleave two C-Cl-bonds of geminal dichlorides via two consecutive S.
配位配体的一个独特特征是具有显著的亲核性并伴有明显的氧化还原非惰性，在当前情况下，这会导致前所未有的以碳为中心的反应模式：一种基于碳二磷烷（CDP）的钳型铑配合物能够通过两个连续的S过程裂解偕二氯化物的两个C-Cl键。
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