Optimizing Stretchability and Electrical Stability in Bilayer-Structured Flexible Liquid Metal Composite Electrodes.

Gallium-based liquid metals remain in a liquid state at room temperature and exhibit excellent electrical and thermal conductivities, low viscosity, and low toxicity, making them ideal for creating highly stretchable and conductive composites suitable for flexible electronic devices. Despite these benefits, conventional single-layer liquid metal composites face challenges, such as liquid metal leakage during deformation (e.g., stretching or bending) and limited elongation due to incomplete integration of the liquid metal within the elastomer matrix. To address these limitations, we introduced a bilayer structure into liquid metal composites, comprising a lower polydimethylsiloxane (PDMS) layer and an upper PDMS-liquid metal mixed layer. In the mixed layer, the liquid metal precipitates, forming a conductive network spanning both layers. This bilayer composite structure demonstrated significantly improved stretchability and elongation compared to pure PDMS or single-layer composites. Additionally, by adjusting the size and content of the liquid metal particles, we optimized the composite's mechanical and electrical properties. Under optimal conditions, spherical liquid metal particles deform into elliptical shapes under tensile stress, increasing conductive pathways and reducing electrical resistance. The combined effects of the bilayer structure and particle shape deformation enhanced the composite's stretchability and elongation, supporting its potential for flexible electronics applications.