-Bis(quinoline-8-amine-κ ,')bis-(1,1,3,3-tetra-cyano-2-meth-oxy-propenido-κ)iron(II).

作者信息

Setifi Fatima, Setifi Zouaoui, Böhme Uwe, Al-Douh Mohammad Hadi, Satour Achouak

机构信息

Laboratoire de Chimie Ingénierie Moléculaire et Nanostructures (LCIMN) Université Ferhat Abbas Sétif 1 Sétif 19000 Algeria.

Départment de Technologie Faculté de Technologie Université 20 Août 1955-Skikda BP 26 Route d'El-Hadaiek Skikda 21000 Algeria.

出版信息

IUCrdata. 2024 Dec 20;9(Pt 12):x241219. doi: 10.1107/S2414314624012197. eCollection 2024 Dec.

DOI:10.1107/S2414314624012197

PMID:39777004

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11701756/

Abstract

The title compound, [Fe(CHNO)(CHN)], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Fe ion is located on an inversion centre. The octa-hedral FeN coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra-cyano-2-meth-oxy-propenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic axis and parallel to (110).

摘要

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3ce/11701756/4b16f764eafd/x-09-x241219-fig1.jpg

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