-双（喹啉-8-胺-κ，'）双-（1,1,3,3-四氰基-2-甲氧基丙烯基-κ）铁（II）
-Bis(quinoline-8-amine-κ ,')bis-(1,1,3,3-tetra-cyano-2-meth-oxy-propenido-κ)iron(II).
作者信息
Setifi Fatima, Setifi Zouaoui, Böhme Uwe, Al-Douh Mohammad Hadi, Satour Achouak
机构信息
Laboratoire de Chimie Ingénierie Moléculaire et Nanostructures (LCIMN) Université Ferhat Abbas Sétif 1 Sétif 19000 Algeria.
Départment de Technologie Faculté de Technologie Université 20 Août 1955-Skikda BP 26 Route d'El-Hadaiek Skikda 21000 Algeria.
出版信息
IUCrdata. 2024 Dec 20;9(Pt 12):x241219. doi: 10.1107/S2414314624012197. eCollection 2024 Dec.
The title compound, [Fe(CHNO)(CHN)], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Fe ion is located on an inversion centre. The octa-hedral FeN coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra-cyano-2-meth-oxy-propenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic axis and parallel to (110).
标题化合物[Fe(CHNO)(CHN)]通过溶剂热法合成。该配合物呈现出扭曲的八面体配位几何构型。铁离子位于对称中心上。八面体的FeN配位球在赤道位置由双齿喹啉 - 8 - 胺构成，而轴向位置则被1,1,3,3 - 四氰基 - 2 - 甲氧基丙烯阴离子占据。晶体结构具有平行于晶轴和(110)的氢键。
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