Li Le, Müller Sven, Petzold Roland, Ritter Tobias
Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany.
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany.
Angew Chem Int Ed Engl. 2025 Jan 27;64(5):e202419931. doi: 10.1002/anie.202419931. Epub 2025 Jan 13.
By leveraging the fast oxidative addition of arylthianthrenium salts (aryl-TT) to palladium(0), a regioselective diazoester installation has been developed. This approach enables the introduction of a diazo moiety to densely functionalized arenes at a late stage. The installed diazo group is amenable to facile further derivatization.
通过利用芳基噻蒽鎓盐（芳基-TT）与钯（0）的快速氧化加成反应，开发了一种区域选择性重氮酯的引入方法。这种方法能够在后期将重氮部分引入到功能密集的芳烃中。所引入的重氮基团易于进行进一步衍生化。
