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用于显示和剂量测定应用的铕激活硅酸钇磷光体的光谱参数和陷阱参数研究

Investigation of Spectroscopic Parameters and Trap Parameters of Eu-Activated YSiO Phosphors for Display and Dosimetry Applications.

作者信息

Verma Neeraj, Michalska-Domańska Marta, Dubey Vikas, Ram Tirath, Kaur Jagjeet, Dubey Neha, Aman Shireen, Manners Ovica, Saji Janita

机构信息

Department of Physics, Government G.S.G.PG. College, Balod 491226, Chhattisgarh, India.

Department of Physics, Government Vishwanath Yadav Tamaskar Post Graduate Autonomous College, Durg 491001, Chhattisgarh, India.

出版信息

Molecules. 2024 Dec 30;30(1):108. doi: 10.3390/molecules30010108.

DOI:10.3390/molecules30010108
PMID:39795164
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11721824/
Abstract

Using the solid-state reaction technique, varied YSiO phosphors activated by europium (Eu) ions at varied concentrations were made at calcination temperatures of 1000 °C and 1250 °C during sintering in an air environment. The XRD technique identified the monoclinic structure, and the FTIR technique was used to analyze the generated phosphors. Photoluminescence emission and excitation patterns were measured using varying concentrations of Eu ions. The optimal strength was observed at a 2.0 mol% concentration. Emission peaks were detected at 582 nm and 589 nm for the D→F transition and at 601 nm, 613 nm, and 632 nm for the D→F transition under 263 nm excitation. Because Eu is naturally bright, these emission peaks show how ions change from one excited state to another. This makes them useful for making phosphors that emit red light for use in optoelectronics and flexible displays. Based on the computed (1931 CIE) chromaticity coordinates for the photoluminescence emission spectra, it was determined that the produced phosphor may be used in light-emitting diodes. The TL glow curve was examined for various doping ion concentrations and durations of UV exposure levels, revealing a broad peak at 183 °C. Using computerized glow curve deconvolution (CGCD), we calculated the kinetic parameters.

摘要

采用固态反应技术,在空气环境中烧结时,于1000℃和1250℃的煅烧温度下制备了不同浓度铕(Eu)离子激活的多种YSiO荧光粉。XRD技术确定了单斜结构,并使用FTIR技术分析生成的荧光粉。使用不同浓度的Eu离子测量光致发光发射和激发模式。在2.0 mol%的浓度下观察到最佳强度。在263 nm激发下,D→F跃迁的发射峰在582 nm和589 nm处被检测到,D→F跃迁的发射峰在601 nm、613 nm和632 nm处被检测到。由于Eu本身发光,这些发射峰显示了离子如何从一个激发态转变为另一个激发态。这使得它们可用于制造用于光电子学和柔性显示器的发红光的荧光粉。基于光致发光发射光谱的计算(1931 CIE)色度坐标,确定所制备的荧光粉可用于发光二极管。研究了不同掺杂离子浓度和紫外线暴露水平持续时间下的热释光发光曲线,在183℃处出现一个宽峰。使用计算机化发光曲线去卷积(CGCD)计算了动力学参数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/2b43bcea21fd/molecules-30-00108-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/9c1bec140563/molecules-30-00108-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/5ab8d36a6bf2/molecules-30-00108-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/3adcee942d53/molecules-30-00108-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/f4fd8177d6ba/molecules-30-00108-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/c12694c53972/molecules-30-00108-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/da39e0ce26d7/molecules-30-00108-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/cd15ec7d7d0f/molecules-30-00108-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/2023b52c5f12/molecules-30-00108-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/2b43bcea21fd/molecules-30-00108-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/9c1bec140563/molecules-30-00108-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/874f4f27e88a/molecules-30-00108-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/052cce0f5d65/molecules-30-00108-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/42d420b65fab/molecules-30-00108-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/4d247433f935/molecules-30-00108-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/5ab8d36a6bf2/molecules-30-00108-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/3adcee942d53/molecules-30-00108-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/f4fd8177d6ba/molecules-30-00108-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/c12694c53972/molecules-30-00108-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/da39e0ce26d7/molecules-30-00108-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/cd15ec7d7d0f/molecules-30-00108-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/2023b52c5f12/molecules-30-00108-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a468/11721824/2b43bcea21fd/molecules-30-00108-g013.jpg

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本文引用的文献

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Red, Green, and Blue Photoluminescence of Ba₂SiO₄:M (M = Eu, Eu, Sr) Nanophosphors.Ba₂SiO₄:M(M = Eu、Eu、Sr)纳米磷光体的红、绿、蓝光致发光
Materials (Basel). 2013 Jul 24;6(8):3079-3093. doi: 10.3390/ma6083079.
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Controlling the energy transfer via multi luminescent centers to achieve white light/tunable emissions in a single-phased X2-type Y2SiO5:Eu(3+),Bi(3+) phosphor for ultraviolet converted LEDs.通过多发光中心控制能量转移以在用于紫外光转换发光二极管的单相X2型Y2SiO5:Eu(3+),Bi(3+)荧光粉中实现白光/可调谐发射。
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A single-phased tunable emission phosphor MgY2Si3O10: Eu(3+), Bi(3+) with efficient energy transfer for white LEDs.
一种用于白光发光二极管的具有高效能量转移的单相可调发射荧光粉MgY2Si3O10:Eu(3+),Bi(3+)
Dalton Trans. 2015 Jan 21;44(3):1102-9. doi: 10.1039/c4dt02114b.
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A computer program for the deconvolution of thermoluminescence glow curves.一种用于热释光发光曲线反卷积的计算机程序。
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