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用珊瑚衍生碳酸钙填料增强的环氧树脂复合材料提高辐射屏蔽能力。

Enhancing Radiation Shielding Capabilities with Epoxy-Resin Composites Reinforced with Coral-Derived Calcium Carbonate Fillers.

作者信息

Tochaikul Gunjanaporn, Tanadchangsaeng Nuttapol, Panaksri Anuchan, Moonkum Nutthapong

机构信息

Faculty of Radiological Technology, Rangsit University, Pathumthani 12000, Thailand.

College of Biomedical Engineering, Rangsit University, Pathumthani 12000, Thailand.

出版信息

Polymers (Basel). 2025 Jan 4;17(1):113. doi: 10.3390/polym17010113.

Abstract

This study investigates the development of epoxy-resin composites reinforced with coral-derived calcium carbonate (CaCO) fillers for enhanced radiation shielding and mechanical properties. Leveraging the high calcium content and density of coral, composites were prepared with filler weight fractions of 0%, 25%, and 50%. SEM and EDS analyses revealed that higher filler concentrations (50%) increased particle agglomeration, affecting matrix uniformity. Mechanical testing showed that while the tensile and flexural strengths decreased with the increased filler content, the compressive strength significantly improved, reaching 135 MPa at a 50% coral content. Radiation shielding evaluations demonstrated enhanced attenuation with a higher filler content, achieving 39.63% absorption at 60 kVp for the 50% coral composite. However, the shielding efficiency was notably lower compared to lead, which achieves over 99% absorption at similar energy levels. These quantitative comparisons highlight the material's limitations in high-radiation environments but emphasize its suitability for moderate shielding applications. Despite their lower shielding efficiency, the composites provide an environmentally friendly and non-toxic alternative to lead, aligning with sustainability goals. Future work should focus on optimizing filler dispersion, mitigating agglomeration, and exploring hybrid systems to enhance the shielding efficiency and mechanical properties. The further quantitative evaluation of parameters such as Zeff and cross-sections is recommended to comprehensively assess the material's performance.

摘要

本研究调查了用珊瑚衍生碳酸钙(CaCO)填料增强的环氧树脂复合材料的发展情况,以提高其辐射屏蔽性能和机械性能。利用珊瑚的高钙含量和密度,制备了填料重量分数为0%、25%和50%的复合材料。扫描电子显微镜(SEM)和能谱分析(EDS)表明,较高的填料浓度(50%)会增加颗粒团聚,影响基体均匀性。力学测试表明,虽然拉伸强度和弯曲强度随填料含量的增加而降低,但抗压强度显著提高,在珊瑚含量为50%时达到135兆帕。辐射屏蔽评估表明,填料含量越高,衰减增强,50%珊瑚复合材料在60千伏峰值电压下的吸收率达到39.63%。然而,与铅相比,其屏蔽效率明显较低,铅在类似能量水平下的吸收率超过99%。这些定量比较突出了该材料在高辐射环境中的局限性,但强调了其适用于中等屏蔽应用。尽管其屏蔽效率较低,但这些复合材料为铅提供了一种环保且无毒的替代品,符合可持续发展目标。未来的工作应集中在优化填料分散、减轻团聚以及探索混合体系以提高屏蔽效率和机械性能。建议进一步对有效原子序数(Zeff)和截面等参数进行定量评估,以全面评估该材料的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2af3/11723263/6a5c81caa7a4/polymers-17-00113-g002.jpg

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