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氮氧化物与挥发性有机化合物的联合催化转化:现状与展望

Combined Catalytic Conversion of NOx and VOCs: Present Status and Prospects.

作者信息

Li Mengzhao, Wang Rui

机构信息

School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China.

出版信息

Materials (Basel). 2024 Dec 25;18(1):39. doi: 10.3390/ma18010039.

Abstract

This article presents a comprehensive examination of the combined catalytic conversion technology for nitrogen oxides (NOx) and volatile organic compounds (VOCs), which are the primary factors contributing to the formation of photochemical smog, ozone, and PM2.5. These pollutants present a significant threat to air quality and human health. The article examines the reaction mechanism and interaction between photocatalytic technology and NH-SCR catalytic oxidation technology, highlighting the limitations of the existing techniques, including catalyst deactivation, selectivity issues, regeneration methods, and the environmental impacts of catalysts. Furthermore, the article anticipates prospective avenues for research, underscoring the necessity for the development of bifunctional catalysts capable of concurrently transforming NOx and VOCs across a broad temperature spectrum. The review encompasses a multitude of integrated catalytic techniques, including selective catalytic reduction (SCR), photocatalytic oxidation, low-temperature plasma catalytic technology, and biological purification technology. The article highlights the necessity for further research into catalyst design principles, structure-activity relationships, and performance evaluations in real industrial environments. This research is required to develop more efficient, economical, and environmentally friendly waste gas treatment technologies. The article concludes by outlining the importance of collaborative management strategies for VOC and NOx emissions and the potential of combined catalytic conversion technology in achieving these goals.

摘要

本文全面考察了氮氧化物(NOx)和挥发性有机化合物(VOCs)的联合催化转化技术,这两种物质是导致光化学烟雾、臭氧和PM2.5形成的主要因素。这些污染物对空气质量和人类健康构成重大威胁。本文研究了光催化技术与NH-SCR催化氧化技术之间的反应机理和相互作用,突出了现有技术的局限性,包括催化剂失活、选择性问题、再生方法以及催化剂对环境的影响。此外,本文还展望了未来的研究方向,强调了开发能够在较宽温度范围内同时转化NOx和VOCs的双功能催化剂的必要性。该综述涵盖了多种集成催化技术,包括选择性催化还原(SCR)、光催化氧化、低温等离子体催化技术和生物净化技术。本文强调了在实际工业环境中进一步研究催化剂设计原理、结构-活性关系和性能评估的必要性。开展此项研究是为了开发更高效、经济和环保的废气处理技术。本文最后概述了VOC和NOx排放协同管理策略的重要性以及联合催化转化技术在实现这些目标方面的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7eb/11721165/a773c81ca86b/materials-18-00039-g001.jpg

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