Syngas Production Improvement from CO2RR Using Cu-Sn Electrodeposited Catalysts.

Electrochemical reduction of CO is an efficient and novel strategy to reduce the amount of this greenhouse-effect pollutant gas in the atmosphere while synthesizing value-added products, all of it with an easy synergy with intermittent renewable energies. This study investigates the influence of different ways of combining electrodeposited Cu and Sn as metallic elements in the electrocatalyst. From there, the use of Sn alone or with a small amount of Cu beneath is investigated, and finally, the best catalyst obtained, which has Sn over a slight Cu layer, is evaluated in consecutive cycles to make an initial exploration of the catalyst durability. As a result of this work, after optimization of the Sn and Cu-based catalysts, it is possible to obtain more than 60% of the organic products of interest, predominantly CO, the main component of syngas. Finally, this great amount of CO is obtained under low cell potential (below 3 V), which is a remarkable result in terms of the cost of the process.