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添加多壁碳纳米管的波特兰水泥包裹钢的腐蚀研究

Study of Corrosion of Portland Cement Embedded Steel with Addition of Multi-Wall Carbon Nanotubes.

作者信息

Gómez-Aristizabal Miguel Angel, Moreno-Vargas Jhoan Mauricio, Echeverry-Cardona Laura María, Restrepo-Parra Elisabeth

机构信息

Laboratorio de Física del Plasma, Universidad Nacional de Colombia Sede Manizales, Campus la Nubia, Km 9 via al Magdalena, Manizales 170007, Colombia.

出版信息

Materials (Basel). 2025 Jan 6;18(1):210. doi: 10.3390/ma18010210.

Abstract

In this study, we research the innovative application of multi-walled carbon nanotubes (MWCNTs) as corrosion inhibitors in Portland cement embedded steel. The physicochemical properties of the dispersion solutions were evaluated, varying the storage time, to analyze their effect on corrosion resistance. Using a dispersion energy of 440 J/g and a constant molarity of 10 mM, stable dispersions were achieved for up to 3 weeks. These dispersions were characterized using Raman spectroscopy, UV-Vis spectroscopy and Zeta potential spectroscopy to assess the stability and structural damage of the MWCNTs. These results show that the addition of MWCNTs not only reduces the porosity of the cement matrix, but also forms an effective barrier against chloride ion intrusion, protecting the reinforcing steel. This approach stands out for combining improved mechanical properties and significant corrosion resistance, representing a promising innovation in the development of more durable construction materials.

摘要

在本研究中,我们探究了多壁碳纳米管(MWCNTs)作为波特兰水泥包裹钢中缓蚀剂的创新应用。评估了分散溶液的物理化学性质随储存时间的变化,以分析它们对耐腐蚀性的影响。使用440 J/g的分散能和10 mM的恒定摩尔浓度,可实现长达3周的稳定分散。利用拉曼光谱、紫外可见光谱和zeta电位光谱对这些分散体进行表征,以评估多壁碳纳米管的稳定性和结构损伤。这些结果表明,添加多壁碳纳米管不仅降低了水泥基体的孔隙率,还形成了有效的氯离子侵入屏障,从而保护了钢筋。这种方法因兼具改善的机械性能和显著的耐腐蚀性而脱颖而出,代表了在开发更耐用建筑材料方面的一项有前景的创新。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e79/11721370/a61c4f994f09/materials-18-00210-g001.jpg

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