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用于室温下氢气泄漏检测的电化学传感器

Electrochemical Sensor for Hydrogen Leakage Detection at Room Temperature.

作者信息

Rîmbu Gimi Aurelian, Pîslaru-Dănescu Lucian, Zărnescu George-Claudiu, Ștefănescu Carmen Alina, Iordoc Mihai, Teișanu Aristofan Alexandru, Telipan Gabriela

机构信息

Department of Energy, Environment and Climate Change, National Institute for Research and Development in Electrical Engineering ICPE-CA, 030138 Bucharest, Romania.

Laboratory of Sensors/Actuators and Energy Harvesting, National Institute for Research and Development in Electrical Engineering ICPE-CA, 030138 Bucharest, Romania.

出版信息

Sensors (Basel). 2025 Jan 5;25(1):264. doi: 10.3390/s25010264.

Abstract

The use of hydrogen as fuel presents many safety challenges due to its flammability and explosive nature, combined with its lack of color, taste, and odor. The purpose of this paper is to present an electrochemical sensor that can achieve rapid and accurate detection of hydrogen leakage. This paper presents both the component elements of the sensor, like sensing material, sensing element, and signal conditioning, as well as the electronic protection and signaling module of the critical concentrations of H. The sensing material consists of a catalyst type Vulcan XC72 40% Pt, from FuelCellStore, (Bryan, TX, USA). The sensing element is based on a membrane electrode assembly (MEA) system that includes a cathode electrode, an ion-conducting membrane type Nafion 117, from FuelCellStore, (Bryan, TX, USA). and an anode electrode mounted in a coin cell type CR2016, from Xiamen Tob New Energy Technology Co., Ltd, (Xiamen City, Fujian Province, China). The electronic block for electrical signal conditioning, which is delivered by the sensing element, uses an INA111, from Burr-Brown by Texas Instruments Corporation, (Dallas, TX, USA). instrumentation operational amplifier. The main characteristics of the electrochemical sensor for hydrogen leakage detection are operation at room temperature so it does not require a heater, maximum amperometric response time of 1 s, fast recovery time of maximum 1 s, and extended range of hydrogen concentrations detection in a range of up to 20%.

摘要

由于氢气具有易燃性和易爆性,且无色、无味、无嗅,将其用作燃料存在诸多安全挑战。本文旨在介绍一种能够快速、准确检测氢气泄漏的电化学传感器。本文介绍了该传感器的组成元件,如传感材料、传感元件和信号调理,以及氢气临界浓度的电子保护和信号模块。传感材料由来自美国德克萨斯州布莱恩市FuelCellStore的Vulcan XC72 40% Pt型催化剂组成。传感元件基于膜电极组件(MEA)系统,该系统包括一个阴极电极、一个来自美国德克萨斯州布莱恩市FuelCellStore的Nafion 117型离子传导膜,以及一个安装在来自中国福建省厦门市的厦门拓博新能源科技有限公司的CR2016型硬币电池中的阳极电极。由传感元件提供的用于电信号调理的电子模块使用了来自美国德克萨斯州达拉斯市德州仪器公司(旗下Burr-Brown)的INA111仪表运算放大器。用于氢气泄漏检测的电化学传感器的主要特性包括:在室温下运行,因此不需要加热器;最大安培响应时间为1秒,快速恢复时间最长为1秒,以及在高达20%的范围内扩展氢气浓度检测范围。

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