Unlocking the Photoluminescence Potential of Tabebuia Rosea Dyes: A Novel Natural Source of Broadband Visible Spectral Fluorescence for OLED Technologies.

This investigation delves into the extraction of polyphenols from the flowers of Tabebuia rosea using a basic maceration approach with acetone, ethanol, and methanol as solvents. The spectroscopic analysis of the dye obtained confirms the existence of functional groups in the polyphenol extract. The study also explores optoelectronic, fluorescence, and photometric characteristics associated with polyphenols. Micro-destructive surface techniques, such as XPS led to the acquisition of detailed information on the extracted polyphenol. The XPS analysis verified the chemical composition of the dyes, revealing that C1s, O1s, and N1s peaks are the main signals for the extracted polyphenols. Additionally, the LC-MS analysis reveals the extract contains significant amounts of active compounds in the polyphenols class, which share a common polyphenol structure. FT-IR spectroscopy confirms the presence of functional groups in the polyphenol dye extract. The optical properties showed a narrow direct bandgap (E= 3.08eV), indirect bandgap (E=2.77eV), high refractive index (n = 1.52), dielectric constant (ε = 8.982), and high optical conductivity (σ = 3.54 x10 S/m) for the polyphenols extracted in methanol solvent. Polyphenols are characterized by high quantum yield, substantial lifetime, and notable Stoke's shift. In addition, these polyphenol dyes demonstrate strong broadband visible spectra and cover a spectrum from blue to green (x = 0.32 → 0.33 and y = 0.33 → 0.38) in different solvent conditions. Such attributes make them advantageous for use in Organic-LEDs and other optoelectronic technologies, underscoring their significant potential in these domains. In addition, polyphenols are important in removing DPPH-free radicals from the environment, contributing to the production of highly antioxidant green materials.