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使用硅烷包覆的氧化铝纳米颗粒提高水基钻井液的流变性能和过滤性能

Enhancing the Rheological and Filtration Performance of Water-Based Drilling Fluids Using Silane-Coated Aluminum Oxide NPs.

作者信息

Ahmed Hullio Imran, Tunio Abdul Haque, Akhtar Waseem, Memon Muddassir Ali, Gabol Nasir Mehmood

机构信息

Institute of Petroleum and Natural Gas Engineering, Mehran University of Engineering and Technology, Jamshoro, Sindh 77150, Pakistan.

Department of Metallurgy & Materials Engineering, Mehran University of Engineering and Technology, Jamshoro, Sindh 76062, Pakistan.

出版信息

ACS Omega. 2024 Dec 19;10(1):955-963. doi: 10.1021/acsomega.4c08116. eCollection 2025 Jan 14.

DOI:10.1021/acsomega.4c08116
PMID:39829441
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11740377/
Abstract

For optimizing the drilling efficiency, nanoparticles (NPs) specifically nanometal oxides have been used in water-based drilling fluids (WBDF). Nano metal oxides improve the rheological and filtration characteristics of the WBDF. However, dispersion instability among pristine nano metals shrinks the performance of the nanometal oxides due to high surface energy. Therefore, this study aims to utilize silane-coated aluminum oxide NPs (S-AlO) as an alternative to widely used pristine aluminum oxide (P-AlO) in water-based drilling fluids. The S-AlO NPs were synthesized using 3-aminopropyl triethoxysilane (APTES). FTIR, XRD, and SEM analyses were carried out to examine the crystalline structure and surface morphology of NPs. Moreover, the rheological and filtration properties of nanowater-based drilling fluids were investigated at low-pressure and low-temperature (LPLT) conditions. The results of experiments revealed that S-AlO NPs significantly upgraded the rheological properties compared to P-AlO NPs. The S-AlO NPs reduced plastic viscosity from 12.6 to 9.6 cP, apparent viscosity from 34.5 to 26.5 cP, and yield point from 46.5 to 39.5 lb/100 ft. The gel strengths (10 s and 10 min) were reduced from 44.5 to 32 lb/100 ft and from 77 to 59 lb/100 ft, respectively. Furthermore, S-AlO NPs enhanced the filtration performance, achieving a 26% reduction in filtrate loss and forming a thinner, more impermeable mud cake than P-AlO NPs. In conclusion, the application of S-AlO NPs in water-based drilling fluid was found to be effective in improving the rheological properties and controlling the filtrate loss effectively under LPLT conditions. The utilization of silane-coated NPs used in this study will open new and novel doors of research in the fields of both drilling engineering and nanotechnology.

摘要

为了优化钻井效率,纳米颗粒(NPs),特别是纳米金属氧化物已被用于水基钻井液(WBDF)中。纳米金属氧化物改善了水基钻井液的流变学和过滤特性。然而,由于原始纳米金属之间的分散不稳定性,高表面能会降低纳米金属氧化物的性能。因此,本研究旨在利用硅烷包覆的氧化铝纳米颗粒(S-AlO)作为水基钻井液中广泛使用的原始氧化铝(P-AlO)的替代品。使用3-氨丙基三乙氧基硅烷(APTES)合成了S-AlO纳米颗粒。进行了傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和扫描电子显微镜(SEM)分析,以研究纳米颗粒的晶体结构和表面形态。此外,还研究了纳米水基钻井液在低压低温(LPLT)条件下的流变学和过滤性能。实验结果表明,与P-AlO纳米颗粒相比,S-AlO纳米颗粒显著提升了流变性能。S-AlO纳米颗粒将塑性粘度从12.6厘泊降低到9.6厘泊,表观粘度从34.5厘泊降低到26.5厘泊,屈服点从46.5磅力/100平方英尺降低到3降低到39.5磅力/100平方英尺。凝胶强度(10秒和10分钟)分别从44.5磅力/100平方英尺降低到32磅力/100平方英尺和从77磅力/100平方英尺降低到59磅力/100平方英尺。此外,S-AlO纳米颗粒增强了过滤性能,使滤失量减少了26%,并形成了比P-AlO纳米颗粒更薄、更致密的泥饼。总之,发现在水基钻井液中应用S-AlO纳米颗粒可有效改善流变性能,并在LPLT条件下有效控制滤失量。本研究中使用的硅烷包覆纳米颗粒的应用将为钻井工程和纳米技术领域打开新的研究大门。

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