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利用绿色水热法从废茶包中合成碳量子点用于检测饮用水中的丙烯酰胺:一种经高效液相色谱 - 光电二极管阵列检测(HPLC - PDA)分析验证的荧光测定法

Green hydrothermal approach for the synthesis of carbon quantum dots from waste tea bags for acrylamide detection in drinking water: A fluorescence assay validated by HPLC-PDA analysis.

作者信息

Sharma Nikhil, Thakur Sweezee, Bains Aarti, Goksen Gulden, Ali Nemat, Ansari Mushtaq Ahmad, Kopsacheili Anna, Proestos Charalampos, Chawla Prince

机构信息

Department of Food Technology and Nutrition, School of Agriculture, Lovely Professional University, Phagwara, 144411, India.

Department of Food Technology and Processing, School of Health Sciences, Amity University, Punjab, Mohali 140306, India.

出版信息

Food Chem X. 2024 Nov 29;25:102043. doi: 10.1016/j.fochx.2024.102043. eCollection 2025 Jan.

Abstract

The study focused on converting tea bag waste into strong fluorescence carbon quantum dots (TBW-CQDs) for the detection of acrylamide in drinking water, antimicrobial activity, and photocatalytic degradation. The TBW-CQDs exhibited blue luminescence and maximum absorbance at 287 nm under UV light and distinctive fluorescence emission and excitation wavelengths at 425 nm and 287 nm, respectively. TBW-CQDs revealed a particle size of 8.12 ± 0.06 nm with a spherical morphology followed by an abundance of 59.29 % carbon and 39.82 % oxygen. For acrylamide extraction from water, the QuEChERS method was established, which exhibited a recovery rate of 97 to 99 %. The fluorescence-based sensor exhibited a low limit of detection of 0.35376 ppm, which was validated by HPLC-PDA (LOD 0.300688 ppm). TBW-CQDs degraded 90.62 % of indigo carmine and 93.19 % of methylene blue under bright sunlight. In conclusion, the fabricated TBW-CQDs provide a promising, cost-effective, and precise approach to acrylamide detection in drinking water.

摘要

该研究聚焦于将茶包废料转化为强荧光碳量子点(TBW-CQDs),用于检测饮用水中的丙烯酰胺、抗菌活性及光催化降解。TBW-CQDs在紫外光下呈现蓝色发光,在287nm处有最大吸光度,其荧光发射波长和激发波长分别为425nm和287nm。TBW-CQDs粒径为8.12±0.06nm,呈球形形态,碳含量为59.29%,氧含量为39.82%。对于从水中萃取丙烯酰胺,建立了QuEChERS方法,回收率为97%至99%。基于荧光的传感器检测限低至0.35376ppm,经高效液相色谱-光电二极管阵列检测(LOD 0.300688ppm)验证。在强光下,TBW-CQDs降解了90.62%的靛蓝胭脂红和93.19%的亚甲基蓝。总之,所制备的TBW-CQDs为饮用水中丙烯酰胺的检测提供了一种有前景、经济高效且精确的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2511/11742584/059afa088db5/ga1.jpg

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