• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

用于增强超级电容性能的TiCT纳米片尺寸工程

Size Engineering of TiCT Nanosheets for Enhanced Supercapacitance Performance.

作者信息

Liu Haosheng, Chang Xin, Li Lu, Zhang Mingyi

机构信息

Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China.

出版信息

Molecules. 2025 Jan 9;30(2):241. doi: 10.3390/molecules30020241.

DOI:10.3390/molecules30020241
PMID:39860112
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11767968/
Abstract

In this research, we synthesized a series of TiCT nanosheets with varying lateral dimensions and conducted a thorough investigation into the profound relationship between the electrochemical performance of TiCT materials and their lateral sizes. This study innovatively incorporates a clever combination of small-sized and large-sized TiCT nanosheets in the electrode preparation process. This strategy yields excellent results at low scan rates, with the fabricated electrode achieving a high volumetric capacitance of approximately 658 F/g. Even more remarkable is the fact that, even under extreme testing conditions where the scan rate surges to 10 V s, the electrode retains its capacitive characteristics robustly without any significant performance degradation. These outstanding characteristics underscore the exceptional ability of TiCT electrode materials to maintain high energy storage capacity during rapid charge-discharge cycles, holding significant importance for advancing the development of electrochemical energy storage devices with fast response times and high power densities.

摘要

在本研究中,我们合成了一系列具有不同横向尺寸的TiCT纳米片,并对TiCT材料的电化学性能与其横向尺寸之间的深层关系进行了深入研究。本研究创新性地在电极制备过程中巧妙地结合了小尺寸和大尺寸的TiCT纳米片。该策略在低扫描速率下产生了优异的结果,制备的电极实现了约658 F/g的高体积电容。更值得注意的是,即使在扫描速率飙升至10 V/s的极端测试条件下,电极仍能稳健地保持其电容特性,而没有任何明显的性能下降。这些突出特性突显了TiCT电极材料在快速充放电循环中保持高能量存储容量的卓越能力,这对于推动具有快速响应时间和高功率密度的电化学储能装置的发展具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/843952a69125/molecules-30-00241-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/c6ea3269103f/molecules-30-00241-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/f9362cd17e75/molecules-30-00241-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/0a067536015a/molecules-30-00241-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/7d6b880af03a/molecules-30-00241-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/ca16b6a6cdaa/molecules-30-00241-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/80ec64a9c717/molecules-30-00241-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/843952a69125/molecules-30-00241-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/c6ea3269103f/molecules-30-00241-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/f9362cd17e75/molecules-30-00241-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/0a067536015a/molecules-30-00241-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/7d6b880af03a/molecules-30-00241-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/ca16b6a6cdaa/molecules-30-00241-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/80ec64a9c717/molecules-30-00241-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd9e/11767968/843952a69125/molecules-30-00241-g007.jpg

相似文献

1
Size Engineering of TiCT Nanosheets for Enhanced Supercapacitance Performance.用于增强超级电容性能的TiCT纳米片尺寸工程
Molecules. 2025 Jan 9;30(2):241. doi: 10.3390/molecules30020241.
2
All-MXene-Based Integrated Membrane Electrode Constructed using TiCT as an Intercalating Agent for High-Performance Desalination.基于全 MXene 的集成膜电极构建,使用 TiCT 作为嵌入剂,用于高性能脱盐。
Environ Sci Technol. 2020 Apr 7;54(7):4554-4563. doi: 10.1021/acs.est.9b05759. Epub 2020 Mar 12.
3
High-Performance Flexible and Symmetric Supercapacitors Based on Micro-Flower-Like MnSe@TiCT Heterostructure.基于微花状MnSe@TiCT异质结构的高性能柔性对称超级电容器
Small. 2025 Jan;21(3):e2409130. doi: 10.1002/smll.202409130. Epub 2024 Nov 24.
4
Anchoring Oxidized MXene Nanosheets on Porous Carbon Nanotube Sponge for Enhancing Ion Transport and Pseudocapacitive Performance.将氧化的MXene纳米片锚定在多孔碳纳米管海绵上以增强离子传输和赝电容性能。
ACS Appl Mater Interfaces. 2022 Sep 21;14(37):41997-42006. doi: 10.1021/acsami.2c10659. Epub 2022 Sep 7.
5
Fabrication of a High-Energy Flexible All-Solid-State Supercapacitor Using Pseudocapacitive 2D-TiCT-MXene and Battery-Type Reduced Graphene Oxide/Nickel-Cobalt Bimetal Oxide Electrode Materials.使用赝电容二维TiCT-MXene和电池型还原氧化石墨烯/镍钴双金属氧化物电极材料制备高能量柔性全固态超级电容器
ACS Appl Mater Interfaces. 2020 Nov 25;12(47):52749-52762. doi: 10.1021/acsami.0c16221. Epub 2020 Nov 13.
6
Synthesis and Fabrication of Metal Cation Intercalation in Multilayered TiCT Composite CNF Electrode for Asymmetric Coin Cell Supercapacitors.用于非对称硬币型电池超级电容器的多层TiCT复合碳纳米纤维电极中金属阳离子嵌入的合成与制备
Langmuir. 2024 Oct 15;40(41):21728-21740. doi: 10.1021/acs.langmuir.4c02822. Epub 2024 Oct 4.
7
A temperature-dependent phosphorus doping on TiCT MXene for enhanced supercapacitance.用于增强超级电容的基于温度的TiCT MXene磷掺杂
J Colloid Interface Sci. 2021 Dec 15;604:239-247. doi: 10.1016/j.jcis.2021.06.020. Epub 2021 Jul 12.
8
In Situ Nitrogen Functionalization of 2D-TiCT-MXenes for High-Performance Zn-Ion Supercapacitor.用于高性能锌离子超级电容器的二维TiCT-MXenes原位氮功能化
Molecules. 2022 Nov 2;27(21):7446. doi: 10.3390/molecules27217446.
9
TiCT Nanosheets/TiCT Quantum Dots/RGO (Reduced Graphene Oxide) Fibers for an All-Solid-State Asymmetric Supercapacitor with High Volume Energy Density and Good Flexibility.用于全固态不对称超级电容器的TiCT纳米片/TiCT量子点/还原氧化石墨烯(RGO)纤维,具有高体积能量密度和良好的柔韧性。
ACS Appl Mater Interfaces. 2020 Mar 11;12(10):11833-11842. doi: 10.1021/acsami.9b21874. Epub 2020 Feb 28.
10
Two-Dimensional Titanium Carbide/RGO Composite for High-Performance Supercapacitors.二维碳化钛/还原氧化石墨烯复合材料用于高性能超级电容器。
ACS Appl Mater Interfaces. 2016 Jun 22;8(24):15661-7. doi: 10.1021/acsami.6b04767. Epub 2016 Jun 10.

本文引用的文献

1
Tuning MXene Properties through Cu Intercalation: Coupled Guest/Host Redox and Pseudocapacitance.通过铜插层调节MXene的性质:客体/主体耦合氧化还原与赝电容
ACS Nano. 2024 Apr 9;18(14):10124-10132. doi: 10.1021/acsnano.3c12989. Epub 2024 Mar 21.
2
Tuning the Microenvironment of Water Confined in TiCT MXene by Cation Intercalation.通过阳离子插层调节TiCT MXene中受限水的微环境
J Phys Chem C Nanomater Interfaces. 2024 Feb 14;128(7):2803-2813. doi: 10.1021/acs.jpcc.4c00247. eCollection 2024 Feb 22.
3
MXene chemistry, electrochemistry and energy storage applications.
MXene 化学、电化学和储能应用。
Nat Rev Chem. 2022 Jun;6(6):389-404. doi: 10.1038/s41570-022-00384-8. Epub 2022 Apr 20.
4
Electrostatic Interfacial Cross-Linking and Structurally Oriented Fiber Constructed by Surface-Modified 2D MXene for High-Performance Flexible Pseudocapacitive Storage.通过表面修饰二维 MXene 构建的静电界面交联和结构导向纤维用于高性能柔性赝电容储能
ACS Nano. 2023 Feb 14;17(3):2487-2496. doi: 10.1021/acsnano.2c10065. Epub 2023 Feb 1.
5
Electrochemically modulated interaction of MXenes with microwaves.电化学调制的 MXenes 与微波的相互作用。
Nat Nanotechnol. 2023 Apr;18(4):373-379. doi: 10.1038/s41565-022-01308-9. Epub 2023 Jan 16.
6
Metal Ion-Induced Porous MXene for All-Solid-State Flexible Supercapacitors.用于全固态柔性超级电容器的金属离子诱导多孔MXene
Nano Lett. 2023 Jan 11;23(1):283-290. doi: 10.1021/acs.nanolett.2c04320. Epub 2022 Dec 25.
7
Thorium(IV) adsorption onto multilayered TiCT MXene: a batch, X-ray diffraction and EXAFS combined study.钍(IV)在多层TiCT MXene上的吸附:批量、X射线衍射和扩展X射线吸收精细结构联合研究。
J Synchrotron Radiat. 2021 Nov 1;28(Pt 6):1709-1719. doi: 10.1107/S160057752101064X.
8
Functionalizing TiCT for enhancing fire resistance and reducing toxic gases of flexible polyurethane foam composites with reinforced mechanical properties.用 TiCT 进行功能化,提高柔性聚氨酯泡沫复合材料的阻燃性和降低其毒性气体,并增强其机械性能。
J Colloid Interface Sci. 2022 Feb;607(Pt 2):1300-1312. doi: 10.1016/j.jcis.2021.09.027. Epub 2021 Sep 25.
9
Understanding and Calibration of Charge Storage Mechanism in Cyclic Voltammetry Curves.循环伏安曲线中电荷存储机制的理解与校准
Angew Chem Int Ed Engl. 2021 Sep 20;60(39):21310-21318. doi: 10.1002/anie.202104167. Epub 2021 Aug 21.
10
2D framework materials for energy applications.用于能源应用的二维框架材料。
Chem Sci. 2020 Dec 23;12(5):1600-1619. doi: 10.1039/d0sc05889k.