探索超分子受阻路易斯酸碱对
Exploring Supramolecular Frustrated Lewis Pairs.
作者信息
Hawkins Paige R, Hawes Chris S, Matthews Peter D
机构信息
School of Chemical and Physical Sciences, Keele University, Keele, ST5 5GB.
出版信息
Chempluschem. 2025 May;90(5):e202400725. doi: 10.1002/cplu.202400725. Epub 2025 Feb 11.
Frustrated Lewis pairs (FLPs) have rapidly become one of the key metal-free catalysts for a variety of chemical transformations. Embedding these catalysts within a supramolecular assembly can offer improvements to factors such as recyclability and selectivity. In this review we discuss advances in this area, covering key supramolecular assemblies such as metal organic frameworks (MOFs), covalent organic frameworks (COFs), polymers and macrocycles.
受阻路易斯酸碱对（FLPs）已迅速成为用于各种化学转化的关键无金属催化剂之一。将这些催化剂嵌入超分子组装体中可以改善诸如可回收性和选择性等因素。在本综述中，我们讨论了该领域的进展，涵盖了关键的超分子组装体，如金属有机框架（MOFs）、共价有机框架（COFs）、聚合物和大环化合物。
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