Metal-ligand cooperativity enables zero-valent metal transfer.

Group 13 aminoxy complexes of the form (L)E(TEMPO) (TEMPO = 2,2,6,6-tetramethylpiperidine 1-oxyl; L = THF (tetrahydrofuran) or Py (pyridine); E = Al, Ga, In) were prepared and structurally characterized. The complexes (THF)Ga(TEMPO) (1·THF) and (Py)In(TEMPO) (2·Py) are shown to heterolytically cleave H under mild conditions (3 atm, 20 °C, ≤ 1 h). 1·THF reacts reversibly with H to form a formal H-adduct that bears a Ga(iii) hydride site and a protonated TEMPO ligand with concomitant loss of THF, consistent with Ga(iii) and TEMPO functioning as Lewis acid and base, respectively. Conversely, 2·Py is reduced by H to form an intermediate dimer complex of monovalent {In(TEMPO)}, which undergoes further reactivity with H to form elemental indium as determined by powder X-ray diffraction. Treatment of 2·Py with H and PhPSe forms binary InSe, in addition to PhP and TEMPOH, demonstrating that 2·Py functions as a molecular source of zero-valent indium under mildly reducing conditions. Computational studies support an intramolecular metal-ligand cooperativity pathway in the heterolytic cleavage of H.