Roy Matthew M D, Omaña Alvaro A, Wilson Andrew S S, Hill Michael S, Aldridge Simon, Rivard Eric
Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom.
Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta T6G 2G2, Canada.
Chem Rev. 2021 Oct 27;121(20):12784-12965. doi: 10.1021/acs.chemrev.1c00278. Epub 2021 Aug 27.
This review serves to document advances in the synthesis, versatile bonding, and reactivity of molecular main group metal hydrides within Groups 1, 2, and 12-16. Particular attention will be given to the emerging use of said hydrides in the rapidly expanding field of Main Group element-mediated catalysis. While this review is comprehensive in nature, focus will be given to research appearing in the open literature since 2001.
本综述旨在记录第1、2以及12 - 16族分子主族金属氢化物在合成、多功能键合及反应活性方面的进展。将特别关注上述氢化物在迅速发展的主族元素介导催化领域中的新应用。尽管本综述内容全面，但重点将放在2001年以来公开文献中出现的研究上。
