Low-Temperature IR Camouflage Materials by Dual Resonances for Enhanced Thermal Management without Energy Consumption.

Due to the critical importance of carbon neutrality for the survival of humanity, passive thermal management, which manages thermal energy without additional energy consumption, has become increasingly attractive. Camouflage materials offer a promising solution for passive thermal management, as they can dissipate heat through thermal radiation, reducing the need for energy-intensive cooling systems. However, developing effective infrared (IR) camouflage solutions for low-temperature environments and small-sized applications remains a challenge because the low temperatures limit the ability to dissipate radiative energy from the surface. Moreover, conventional IR camouflage materials, typically optimized for single band (5-8 μm), face significant limitations in energy dissipation at lower temperatures, which requires a novel way to increase the energy dissipation without the additional energy consumption. Herein, we present a novel low-temperature IR camouflage material (LICM) designed to address these challenges by employing dual-band resonances in the nondetection bands, 5-8 and 14-20 μm based on the atmospheric transmittance. LICM demonstrated an increase in energy dissipation of 273 and 167% at 250 and 350 K, respectively than the conventional IR camouflage materials. Despite the enhanced dissipation, the LICM maintained an IR signature reduction of around 10% of blackbody radiation, ensuring effective IR camouflage. Thermographic measurements using an LWIR camera (7.5-14 μm) further demonstrated the LICM's superior IR camouflage performance. This dual-band resonance design not only extends IR camouflage to low-temperature environments but also facilitates significant energy savings, making it a key ingredient for broad-scale deployment in areas such as energy conversion, aerospace, and sustainable thermal management technologies.