Stability challenges of transition metal-modified cathodes for electro-Fenton process: A mini-review.

Electro-Fenton (EF) process with transition-metal (TM) modified cathode has been regarded as a green and promising technology for wastewater treatment. Recently, breakthroughs in boosting catalyst activity for both two-electron oxygen reduction reaction (2e ORR) and Fenton's reaction have gained intensive attention. However, achieving long-term stability of catalysts remains challenging, but is decisive for large-scale applications. This minireview provides fundamental understanding on the activity-stability correlation and the deactivation mechanisms of TM-based catalysts in EF systems, focusing on physical and chemical evolution, metal dissolution, catalyst detachment and structure collapse during long-term electrolysis. Subsequently, ongoing efforts from catalyst design to electrode engineering to stabilize the metal active sites are highlighted. Finally, the challenges and future perspectives in developing active and durable TM-modified cathodes are discussed, serving as a roadmap towards the large-scale application of EF process for wastewater treatment.