Miguel-Casañ Eugenia, Orton Georgia R F, Schier Danielle E, Champness Neil R
School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK.
Adv Mater. 2025 Feb 2:e2414509. doi: 10.1002/adma.202414509.
Far from being simply rigid, benign architectures, metal-organic frameworks (MOFs) exhibit diverse interactions with their interior environment. From developing crystal sponges to studying reactions in framework materials, the role of both supramolecular chemistry and framework structure is evident. We explore the role of supramolecular chemistry in determining framework…guest interactions and attempts to understand the dynamic behavior in MOFs, including attempts to control pore behavior through the incorporation of mechanically-interlocked molecules. Appreciating and understanding the role of supramolecular interactions and dynamic behavior in metal-organic frameworks emerge as important directions for the field.
金属有机框架（MOFs）远非简单的刚性良性结构，而是与内部环境表现出多样的相互作用。从开发晶体海绵到研究框架材料中的反应，超分子化学和框架结构的作用都很明显。我们探讨了超分子化学在确定框架……客体相互作用中的作用，并试图理解金属有机框架中的动态行为，包括通过引入机械互锁分子来控制孔隙行为的尝试。认识和理解超分子相互作用及动态行为在金属有机框架中的作用已成为该领域的重要方向。
