Didaran Aida, Sadeghi Mahnaz Sadat, Manavi Parisa Nejatkhah, Rabbani Mohammad
Department of Marine Biology North Tehran Branch, Islamic Azad University Tehran Iran.
Department of Marine Chemistry North Tehran Branch, Islamic Azad University Tehran Iran.
Glob Chall. 2025 Jan 7;9(2):2400107. doi: 10.1002/gch2.202400107. eCollection 2025 Feb.
Scientists are constantly striving to develop improved methods for reducing or eliminating the discharge of harmful heavy metals into drinking water sources and the environment. In light of this, this study investigates the potential of utilizing a naturally available and sustainable bio-waste material, cuttlebone Powder (SCP), as an exceptionally effective adsorbent for the adsorption of Ni (II), Pb (II), Cu (II), and Fe (II) ions. SCP is also characterized by Fourier-transform infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Xray diffraction (XRD), and Energy dispersive Xray (EDX) analysis. The results reveal that the highest absorption values for Ni (II), Cu (II), and Fe (II) ions are observed at pH 8, while Pb (II) ions exhibit the highest absorption at pH 4. The absorption percentage of the ions displays an increasing trend with the amount of SCP used, as well as with contact time and magnetizing SCP duration. Additionally, the addition of FeO to SCP significantly improves the absorption rate of the samples. Both Langmuir and Freundlich adsorption models are found to fit the experimental data well. Overall, SCP, with or without FeO nanoparticles, shows great promise for water remediation processes by effectively removing heavy metals.
科学家们一直在努力开发改进的方法,以减少或消除有害重金属向饮用水源和环境中的排放。鉴于此,本研究调查了利用天然可得且可持续的生物废料——乌贼骨粉(SCP)作为吸附Ni(II)、Pb(II)、Cu(II)和Fe(II)离子的高效吸附剂的潜力。还通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、X射线衍射(XRD)和能量色散X射线(EDX)分析对SCP进行了表征。结果表明,Ni(II)、Cu(II)和Fe(II)离子在pH值为8时观察到最高吸收值,而Pb(II)离子在pH值为4时表现出最高吸收。离子的吸收百分比随着SCP用量、接触时间和SCP磁化时间的增加而呈上升趋势。此外,向SCP中添加FeO显著提高了样品的吸收速率。发现朗缪尔吸附模型和弗伦德利希吸附模型都能很好地拟合实验数据。总体而言,无论有无FeO纳米颗粒,SCP通过有效去除重金属在水修复过程中都显示出巨大的潜力。