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金（I）、金（II）、金（III）氟化物配合物：合成及其在有机转化中的应用

Au(I)-, Au(II)-, Au(III)-Fluoride Complexes: Synthesis and Applications in Organic Transformations.

作者信息

Sedikides Alexi T, Walters Rhian C, Dean Alice C, Lennox Alastair J J

机构信息

School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.

出版信息

Angew Chem Int Ed Engl. 2025 Apr 17;64(17):e202424656. doi: 10.1002/anie.202424656. Epub 2025 Feb 26.

DOI:10.1002/anie.202424656
PMID:39932295
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12015403/
Abstract

The synthesis and reactivity of organometallic gold-fluoride complexes in oxidation states of Au, Au, and Au, up to and including 2024, are reviewed herein. Despite the flourishing field of gold catalysis, these complexes had long been elusive due to their instability. A widespread interest in C-C and C-F coupling reactions has resulted in several reports of these complexes in recent years. The use of a variety of supporting ligands have facilitated access to these complexes, which has allowed their reactivity to be further studied and understood, thereby laying the ground for future reaction development. This review highlights these advances, organised by the formal oxidation state of the gold centre and the supporting ligand.

摘要

本文综述了截至2024年包括Au(I)、Au(II)和Au(III)氧化态的有机金属金氟配合物的合成及反应活性。尽管金催化领域蓬勃发展，但由于这些配合物不稳定，长期以来难以捉摸。近年来，对碳-碳和碳-氟偶联反应的广泛关注导致了这些配合物的多篇报道。多种支持配体的使用促进了这些配合物的获取，从而能够进一步研究和理解它们的反应活性，为未来反应的发展奠定了基础。本综述重点介绍了这些进展，按金中心的形式氧化态和支持配体进行组织。

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