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化合价的化学理论。

The chemical theory of valence.

作者信息

Brown Ian David

机构信息

Brockhouse Institute for Materials Research, McMaster University, Hamilton, Ontario L8S 4M1, Canada.

出版信息

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2025 Apr 1;81(Pt 2):164-7. doi: 10.1107/S2052520625000022.

Abstract

Relaxing the restriction that valence can only adopt integer values removes the distinction between ionic and covalent bonds, resulting in a simple and powerful valence theory using the concept of the bonding strength of an element, defined as the ratio of its atomic valence to its average coordination number. Bonding strength, closely related to electronegativity, determines which atoms form stable bonds and the chemical properties of the resulting compounds of both organic and inorganic compounds.

摘要

放宽化合价只能取整数值的限制,消除了离子键和共价键之间的区别,从而产生了一种简单而强大的化合价理论,该理论使用元素的键合强度概念,定义为其原子价与其平均配位数之比。键合强度与电负性密切相关,它决定了哪些原子形成稳定的键以及由此产生的有机和无机化合物的化学性质。

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本文引用的文献

1
Empirical Lewis acid strengths for 135 cations bonded to oxygen.与氧键合的135种阳离子的经验路易斯酸强度
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017 Oct 1;73(Pt 5):956-961. doi: 10.1107/S2052520617010988. Epub 2017 Sep 28.
2
Bond-length distributions for ions bonded to oxygen: alkali and alkaline-earth metals.与氧键合的离子的键长分布:碱金属和碱土金属。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Aug 1;72(Pt 4):602-25. doi: 10.1107/S2052520616008507.
3
Comprehensive derivation of bond-valence parameters for ion pairs involving oxygen.涉及氧的离子对的键价参数的全面推导。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015 Oct;71(Pt 5):562-78. doi: 10.1107/S2052520615016297. Epub 2015 Sep 30.
5
Prediction of the crystal structures of perovskites using the software program SPuDS.使用软件程序SPuDS预测钙钛矿的晶体结构。
Acta Crystallogr B. 2001 Dec;57(Pt 6):725-38. doi: 10.1107/S0108768101015282. Epub 2001 Nov 29.

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