Lai Xintao, Li Tongyu, Hou Xiaoyu, Vogelbacher Florian, Wang Jiajun, Song Yanlin, Shi Lei, Li Mingzhu
Key Laboratory of Bio-Inspired Materials and Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Proc Natl Acad Sci U S A. 2025 Mar 4;122(9):e2419113122. doi: 10.1073/pnas.2419113122. Epub 2025 Feb 25.
Artificial chiral-structural-color materials can carry high-dimensional information based on multiple optical degrees of freedom, providing possibilities for advanced optical security and information storage. However, current artificial chiral-structural-color materials are hindered by their specific compositions, fine nanostructures, and single polarization modulation. Here, we found that microdomes made from common polymers have chiral structural colors with broadband tunability and multiple polarization-modulated chirality. The microdome patterns are easily fabricated by ordinary printing techniques and have inhomogeneous spatial distributions of full polarization states and customizable colors. Our chiral-structural-color microdomes (CSCMs) provide a promising roadmap for high-capacity information encryption and high-security anti-counterfeiting. We developed multidimensional tunable structural color displays and achieved encryption with high information capacity. To further highlight the application potential, we constructed contact lenses integrated with CSCMs for identity authentication with 2 distinctive cryptograms.
人工手性结构色材料可以基于多个光学自由度携带高维信息,为先进的光学安全和信息存储提供了可能性。然而,目前的人工手性结构色材料受到其特定组成、精细纳米结构和单一偏振调制的限制。在这里,我们发现由普通聚合物制成的微穹顶具有宽带可调谐性和多偏振调制手性的手性结构色。微穹顶图案很容易通过普通印刷技术制造,并且具有全偏振态的不均匀空间分布和可定制颜色。我们的手性结构色微穹顶(CSCM)为高容量信息加密和高安全性防伪提供了一条很有前景的途径。我们开发了多维可调谐结构色显示器,并实现了具有高信息容量的加密。为了进一步突出其应用潜力,我们构建了集成有CSCM的隐形眼镜,用于通过2种独特的密码进行身份认证。