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用于柔性传感器的含聚硫辛酸动态网络的透明可回收离子凝胶

Transparent and Recyclable Ionogels Enabled by Dynamic Networks Containing Poly(Thioctic Acid) for Flexible Sensors.

作者信息

Fang Tian Xing, Qiu Wenlian, He Zi Feng, Lan Ming Hui, Zhu Dong Yu, Qiu Xueqing

机构信息

Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China.

Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang, 515200, China.

出版信息

Macromol Rapid Commun. 2025 Feb 26:e2401091. doi: 10.1002/marc.202401091.

Abstract

Ionogels filled with non-volatile ionic liquids effectively mitigate issues such as solvent volatilization, making them suitable for flexible sensors. However, it remains challenging to fabricate recyclable ionogels with outstanding mechanical properties, high transparency, and recyclable capabilities. In this study, a transparent ionogel with dynamic networks is prepared by in situ polymerization of thioctic acid (TA) with polyvinyl pyrrolidone (PVP) in a halometallate ionic liquid. Due to the abundant dynamic crosslinks formed between the halometallate ionic liquid and PTA along with the rigidity of PVP, the ionogels exhibited excellent mechanical strength (≈6.14 MPa), satisfying stretchability (≈1000%), and high toughness (≈20.08 MJ m). Meanwhile, the ionogel displayed high transparency, UV shielding capability, recyclability, and reprocessability. Enabled by the electrochemical properties, the ionogel can be used for flexible sensors, demonstrating good sensitivity and stability for repeatable use. This work provides a straightforward approach for synthesizing high-performance ionogels for flexible sensing applications.

摘要

填充有非挥发性离子液体的离子凝胶可有效缓解诸如溶剂挥发等问题,使其适用于柔性传感器。然而,制备具有出色机械性能、高透明度和可回收能力的可回收离子凝胶仍然具有挑战性。在本研究中,通过硫辛酸(TA)与聚乙烯吡咯烷酮(PVP)在卤金属酸盐离子液体中原位聚合制备了具有动态网络的透明离子凝胶。由于卤金属酸盐离子液体与PTA之间形成了丰富的动态交联以及PVP的刚性,离子凝胶表现出优异的机械强度(≈6.14兆帕)、令人满意的拉伸性(≈1000%)和高韧性(≈20.08兆焦/平方米)。同时,该离子凝胶具有高透明度、紫外线屏蔽能力、可回收性和可再加工性。基于其电化学性质,该离子凝胶可用于柔性传感器,在重复使用时表现出良好的灵敏度和稳定性。这项工作为合成用于柔性传感应用的高性能离子凝胶提供了一种直接的方法。

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