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清代严重受损纸质档案的特征描述与修复

Characterisation and restoration of a severely damaged paper archive from the Qing Dynasty.

作者信息

Liu Panpan, Li Yanli, Li Huimin, Zhang WenYue, Qi Yunpeng, Zhang Xiaoya, Luo Yujia, Li Yuhu

机构信息

Engineering Research Center of Historical Cultural Heritage Conservation, Ministry of Education, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119, China.

The Archives of Xi'an Jiaotong University, Xi'an, 710049, China.

出版信息

Sci Rep. 2025 Mar 3;15(1):7380. doi: 10.1038/s41598-025-92134-1.

Abstract

In this study, a severely damaged official document produced in the Qing Dynasty (1911 A.D.), was characterized using a range of techniques and subsequently restored using the traditional Chinese conservation methods. The pH and crystalline index of the paper were measured using a pH meter, attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR), and X-ray Diffraction (XRD) spectroscopy. The results indicate that the paper archive is acidic and degraded, which is also supported by the broken fibres as observed using scanning electron microscopy (SEM). Then, the properties and durability of the conservation materials, including the conservation paper made of Wikstroemia fibre and wheat starch paste, were explored by determination of colour difference, whiteness, pH, tensile strength, and observation of cross-sectional features before and after dry- and moist-heat degradation. The results demonstrate the conservation materials presented good durability and were then used to perform subsequent conservation treatments, including the assembly of paper pieces and the application of backing paper, to provide additional mechanical support for the preservation of the historical paper archive.

摘要

在本研究中,对一份严重受损的清代(公元1911年)官方文件采用一系列技术进行表征,随后使用中国传统修复方法进行修复。使用pH计、衰减全反射傅里叶变换红外光谱(ATR-FTIR)和X射线衍射(XRD)光谱测量纸张的pH值和结晶指数。结果表明,该纸质档案呈酸性且已降解,扫描电子显微镜(SEM)观察到的纤维断裂也证实了这一点。然后,通过测定色差、白度、pH值、拉伸强度以及观察干热和湿热降解前后的横截面特征,探究了包括狼毒纤维保护纸和小麦淀粉糊在内的修复材料的性能和耐久性。结果表明这些修复材料具有良好的耐久性,随后用于进行后续修复处理,包括纸片拼接和裱褙,为保存历史纸质档案提供额外的机械支撑。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2da9/11873124/98bea73a5abb/41598_2025_92134_Fig1_HTML.jpg

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