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在橄榄油生产链中再利用橄榄果渣废弃物:膜技术如何从废水中回收营养物质。

Reusing wastes from olive pomace in oil production chain: How membrane technology can rescue nutrients from wastewaters.

作者信息

Cassano Alfredo, Calandra Pietro, Caputo Paolino, Morelli Rosanna, Conidi Carmela, Argurio Pietro, Rossi Cesare Oliviero

机构信息

National Research Council - Institute on Membrane Technology (CNR-ITM), c/o University of Calabria, Via P. Bucci, 17C, 87036, Rende, CS, Italy.

National Research Council, CNR-ISMN, Strada provinciale 35D n.9 - 00010, Montelibretti, RM, Italy.

出版信息

Heliyon. 2025 Feb 12;11(4):e42653. doi: 10.1016/j.heliyon.2025.e42653. eCollection 2025 Feb 28.

DOI:10.1016/j.heliyon.2025.e42653
PMID:40028581
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11872428/
Abstract

In olive oil production, once high-grade oils (extra virgin olive oil and virgin olive oil) are produced by milling procedure, further oils are then recovered by different methods. The lowest grade is pomace oil, recovered usually by solvent techniques, from oil pomace. This step is important for the oil recovery, but environmental issue need to be faced, since the stocking and treatment of pomace oil causes emissions into the atmosphere with fumes and smells. The present work was aimed at evaluating the performance of nanofiltration (NF) and reverse osmosis (RO) processes in the treatment of wastewaters coming from the condensation of steam emissions in a pomace oil factory. This approach allowed to reduce the volume of condensed wastewaters producing two valuable streams: fresh water, as permeate stream, and a nutrient-rich solution, as retentate stream. The experimental results indicated a better performance of the RO membrane with a progressive increase of total organic carbon (TOC), conductivity and total polyphenols in the retentate of the process. This solution can be further dehydrated and reused as organic fertilizer. The purified water, produced as permeate, can be re-used within the plant itself (i.e. water replenishment of evaporative towers or as boiler feed after degassing) or in other processes (i.e. irrigation, machinery washing, etc.).

摘要

在橄榄油生产中,一旦通过研磨工序生产出高档油(特级初榨橄榄油和初榨橄榄油),随后便会通过不同方法回收更多的油。最低等级的是果渣油,通常通过溶剂技术从油渣中回收。这一步骤对于油的回收很重要,但需要面对环境问题,因为果渣油的储存和处理会导致废气和异味排放到大气中。本研究旨在评估纳滤(NF)和反渗透(RO)工艺处理来自果渣油工厂蒸汽排放冷凝水的性能。这种方法能够减少冷凝废水的体积,产生两种有价值的流:作为渗透物流的淡水和作为截留物流的富含营养的溶液。实验结果表明,随着该工艺截留物中总有机碳(TOC)、电导率和总多酚含量的逐渐增加,RO膜表现出更好的性能。这种溶液可以进一步脱水并作为有机肥料再利用。作为渗透物产生的净化水可以在工厂内部重新使用(例如补充蒸发塔的水或脱气后作为锅炉给水)或用于其他工艺(例如灌溉、机器清洗等)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/4bf6ab7342c1/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/1c978d7e6178/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/6c2c885f1685/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/1c32ee82f9e6/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/aeeeed1a0ae2/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/4bf6ab7342c1/gr5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/1c978d7e6178/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/6c2c885f1685/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/1c32ee82f9e6/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/aeeeed1a0ae2/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c61d/11872428/4bf6ab7342c1/gr5.jpg

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本文引用的文献

1
Olive mill wastes: from wastes to resources.橄榄压榨废料:变废为宝。
Environ Sci Pollut Res Int. 2024 Mar;31(14):20853-20880. doi: 10.1007/s11356-024-32468-x. Epub 2024 Feb 26.
2
Hydroxytyrosol recovery from olive pomace: a simple process using olive mill industrial equipment and membrane technology.从橄榄果渣中回收羟基酪醇:一种使用橄榄油压榨工业设备和膜技术的简单工艺。
J Food Sci Technol. 2024 Jan;61(1):161-168. doi: 10.1007/s13197-023-05832-x. Epub 2023 Sep 20.
3
Obtaining an Extract Rich in Phenolic Compounds from Olive Pomace by Pressurized Liquid Extraction.
采用加压液体萃取法从橄榄渣中提取富含酚类化合物的提取物。
Molecules. 2019 Aug 27;24(17):3108. doi: 10.3390/molecules24173108.
4
Treatment of Flue Gas Desulfurization Wastewater by an Integrated Membrane-Based Process for Approaching Zero Liquid Discharge.基于膜集成工艺处理烟气脱硫废水以实现近零液体排放
Membranes (Basel). 2018 Nov 26;8(4):117. doi: 10.3390/membranes8040117.
5
Recovery of hydroxytyrosol rich extract from two-phase Chemlali olive pomace by chemical treatment.通过化学处理从两相 Chemlali 橄榄渣中回收富含羟基酪醇的提取物。
J Food Sci. 2012 Oct;77(10):C1077-83. doi: 10.1111/j.1750-3841.2012.02898.x. Epub 2012 Aug 31.