Cassano Alfredo, Calandra Pietro, Caputo Paolino, Morelli Rosanna, Conidi Carmela, Argurio Pietro, Rossi Cesare Oliviero
National Research Council - Institute on Membrane Technology (CNR-ITM), c/o University of Calabria, Via P. Bucci, 17C, 87036, Rende, CS, Italy.
National Research Council, CNR-ISMN, Strada provinciale 35D n.9 - 00010, Montelibretti, RM, Italy.
Heliyon. 2025 Feb 12;11(4):e42653. doi: 10.1016/j.heliyon.2025.e42653. eCollection 2025 Feb 28.
In olive oil production, once high-grade oils (extra virgin olive oil and virgin olive oil) are produced by milling procedure, further oils are then recovered by different methods. The lowest grade is pomace oil, recovered usually by solvent techniques, from oil pomace. This step is important for the oil recovery, but environmental issue need to be faced, since the stocking and treatment of pomace oil causes emissions into the atmosphere with fumes and smells. The present work was aimed at evaluating the performance of nanofiltration (NF) and reverse osmosis (RO) processes in the treatment of wastewaters coming from the condensation of steam emissions in a pomace oil factory. This approach allowed to reduce the volume of condensed wastewaters producing two valuable streams: fresh water, as permeate stream, and a nutrient-rich solution, as retentate stream. The experimental results indicated a better performance of the RO membrane with a progressive increase of total organic carbon (TOC), conductivity and total polyphenols in the retentate of the process. This solution can be further dehydrated and reused as organic fertilizer. The purified water, produced as permeate, can be re-used within the plant itself (i.e. water replenishment of evaporative towers or as boiler feed after degassing) or in other processes (i.e. irrigation, machinery washing, etc.).
在橄榄油生产中,一旦通过研磨工序生产出高档油(特级初榨橄榄油和初榨橄榄油),随后便会通过不同方法回收更多的油。最低等级的是果渣油,通常通过溶剂技术从油渣中回收。这一步骤对于油的回收很重要,但需要面对环境问题,因为果渣油的储存和处理会导致废气和异味排放到大气中。本研究旨在评估纳滤(NF)和反渗透(RO)工艺处理来自果渣油工厂蒸汽排放冷凝水的性能。这种方法能够减少冷凝废水的体积,产生两种有价值的流:作为渗透物流的淡水和作为截留物流的富含营养的溶液。实验结果表明,随着该工艺截留物中总有机碳(TOC)、电导率和总多酚含量的逐渐增加,RO膜表现出更好的性能。这种溶液可以进一步脱水并作为有机肥料再利用。作为渗透物产生的净化水可以在工厂内部重新使用(例如补充蒸发塔的水或脱气后作为锅炉给水)或用于其他工艺(例如灌溉、机器清洗等)。