Zuieva Sofiia, Chen Xin
Institute of Chemistry and Biochemistry, Freie Universität Berlin, Altensteinstraße 23a, 14195, Berlin, Germany.
Angew Chem Int Ed Engl. 2025 Apr 25;64(18):e202424932. doi: 10.1002/anie.202424932. Epub 2025 Apr 1.
The integration of 2D materials with molecular chemistry to create molecule-2D material heterostructures presents a compelling strategy for advancing material design and applications. This approach provides precise control over the structure and properties of 2D materials, effectively addressing challenges in their production and fabrication. Among these, molecule-2D transition metal dichalcogenide (mTMD) heterostructures have garnered significant attention due to their distinctive electronic, optical, and catalytic properties, as well as the intriguing emergent states and phenomena resulting from interactions with adjacent molecular and material layers. Achieving the desired electronic and optical properties in these heterostructures hinges on carefully controlling the interactions at the molecule/TMD interfaces. This minireview highlights recent progress in mTMD heterostructures, emphasizing the principles underlying interface interactions, molecular arrangement, and innovative synthetic methodologies.
将二维材料与分子化学相结合以创建分子-二维材料异质结构，为推进材料设计与应用提供了一种极具吸引力的策略。这种方法能够精确控制二维材料的结构和性能，有效应对其生产与制造过程中的挑战。其中，分子-二维过渡金属二硫属化物（mTMD）异质结构因其独特的电子、光学和催化性能，以及与相邻分子和材料层相互作用产生的有趣新兴态和现象而备受关注。在这些异质结构中实现所需的电子和光学性能取决于对分子/TMD界面相互作用的精确控制。本综述重点介绍了mTMD异质结构的最新进展，强调了界面相互作用、分子排列和创新合成方法背后的原理。
