Lu Yingbing, Lei Yu, Cheng Danpeng, Long Lu, He Xiaoxuan, Liu Caiming, Wen Herui, Liu Suijun, Zhu Shuidong
College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Molecules. 2025 Feb 27;30(5):1086. doi: 10.3390/molecules30051086.
Multifunctional materials bearing photoluminescence, single-molecule magnet (SMM) behavior, and proton conduction have been particularly attractive for various promising applications in optics, molecular spintronics, high-density data storage, and fuel cells. However, these kinds of multifunctional systems have rarely been reported. Herein, a Dy-SMM together with luminescent and proton-conducting properties, [Dy(1-tza)(phen)]∙(ClO)∙(HO) (, 1-tza = 2-(1H-tetrazol-1-yl)acetic, phen = 1,10-phenanthroline), was prepared and structurally characterized. Complex features a dinuclear structure bridged by carboxylate oxygen atoms of the 1-tza ligands, and its supramolecular network contains a 1D stacking channel. Complex exhibits strong room-temperature Dy characteristic emissions and SMM behaviors. In addition, complex shows a moderate proton conductivity with 4.00 × 10 S cm at 37 °C and 100% R.H. (R.H. = Relative Humidity), which may be ascribed to the 1D-extended H-bonds in the 1D stacking channel of .
具有光致发光、单分子磁体（SMM）行为和质子传导功能的多功能材料，对于光学、分子自旋电子学、高密度数据存储和燃料电池等各种有前景的应用特别有吸引力。然而，这类多功能体系鲜有报道。在此，制备并对结构进行了表征的一种具有发光和质子传导性质的Dy-SMM，即[Dy(1-tza)(phen)]∙(ClO)∙(HO)（其中1-tza = 2-(1H-四氮唑-1-基)乙酸，phen = 1,10-菲咯啉）。配合物具有由1-tza配体的羧酸根氧原子桥连的双核结构，其超分子网络包含一个一维堆积通道。配合物在室温下表现出强烈的Dy特征发射和SMM行为。此外，配合物在37 °C和100%相对湿度（R.H. = 相对湿度）下显示出4.00 × 10 S cm的适度质子传导率，这可能归因于其在一维堆积通道中的一维扩展氢键。
