Tamošaitis Gintautas, Vaičiukynienė Danutė
Building Materials and Structures Research Centre, Faculty of Civil Engineering and Architecture, Kaunas University of Technology, Studentu st. 48, Kaunas LT-51367, Lithuania.
Materials (Basel). 2025 Feb 27;18(5):1076. doi: 10.3390/ma18051076.
This paper focuses on the alkaline activation of municipal waste incineration (MSWI) bottom ash to create a dense, non-porous composite structure. Normally, high pH solutions are used to activate MSWI bottom ash, but this has the side effect of creating residual effects in the bottom ash. Due to the uniqueness of the incineration process, the bottom ash retains metallic aluminum, which reacts with the alkali to produce hydrogen gas, which forms a porous structure in the sample during the hardening of the composite. This study demonstrates a method of eliminating this effect by lowering the pH of the alkaline activator below 12.5. An alkali-activated binder was prepared from ground MSWI bottom ash as a precursor and a triple alkali activator: NaOH solution, soluble glass (SG) and silica gel waste (SW). The highest compressive strengths of about 20 MPa were achieved for alkali-activated MSWI bottom ash with triple alkali activators such as sodium hydroxide, soluble glass and silica gel waste.
本文着重研究城市垃圾焚烧(MSWI)底灰的碱激发,以形成致密、无孔的复合结构。通常,高pH值溶液用于激发MSWI底灰,但这会在底灰中产生残留效应。由于焚烧过程的特殊性,底灰中保留了金属铝,其与碱反应生成氢气,在复合材料硬化过程中会在样品中形成多孔结构。本研究展示了一种通过将碱性激发剂的pH值降低至12.5以下来消除这种效应的方法。以磨细的MSWI底灰为前驱体,与三元碱性激发剂:氢氧化钠溶液、水玻璃(SG)和硅胶废料(SW)制备了碱激发胶凝材料。使用氢氧化钠、水玻璃和硅胶废料等三元碱性激发剂的碱激发MSWI底灰实现了约20MPa的最高抗压强度。