Mota João, Viana André, Martins Cátia, Pais Adriana C S, Santos Sónia A O, Silvestre Armando J D, Machado José Pedro, Rocha Sílvia M
LAQV-REQUIMTE & Department of Chemistry, University of Aveiro, Campus Universitário Santiago, 3810-193 Aveiro, Portugal.
CICECO-Aveiro Institute of Materials & Department of Chemistry, University of Aveiro, Campus Universitário Santiago, 3810-193 Aveiro, Portugal.
Foods. 2025 Feb 25;14(5):783. doi: 10.3390/foods14050783.
The physicochemical and sensory properties of wines are influenced by several factors, starting in the vineyard and evolving during the winemaking stages. After bottling, variables such as bottle position, closure type, storage temperature, and storage time shape wine characteristics. In this study, red wines stored for approximately 0.5 and 3 years with natural cork, micro-agglomerated cork stoppers, and screw cap closures were analyzed. Various techniques were employed to investigate changes during bottle storage, including the determination of volatile components by comprehensive gas chromatography-mass spectrometry with time-of-flight analyzer (GC × GC-ToFMS), phenolic profile by ultra-high-performance liquid chromatography, coupled with tandem mass spectrometry (UHPLC-DAD-MS), general physicochemical parameters, the oxygen transfer rate of cork stoppers, and sensorial analysis performed by a trained panel. The results revealed that the type of closure created distinct environments within the bottles, slightly influencing both sensory attributes and chemical evolution of the red wines. These findings highlight the value of combining diverse analytical techniques to reveal closure-driven differences, with volatile compound profiling emerging as the most sensitive methodology. Additionally, this study emphasizes that differences modulated by the wine-closure pairing, which become more pronounced during storage, can serve as an oenological tool in the construction of a wine's identity.
葡萄酒的物理化学和感官特性受多种因素影响,始于葡萄园,并在酿酒阶段不断演变。装瓶后,诸如瓶身位置、封瓶类型、储存温度和储存时间等变量会塑造葡萄酒的特性。在本研究中,对使用天然软木塞、微聚集体软木塞和螺旋瓶盖储存约0.5年和3年的红葡萄酒进行了分析。采用了各种技术来研究瓶储期间的变化,包括使用飞行时间分析仪的全二维气相色谱 - 质谱联用仪(GC×GC - ToFMS)测定挥发性成分、超高效液相色谱 - 串联质谱联用仪(UHPLC - DAD - MS)分析酚类成分、常规理化参数、软木塞的氧气透过率,以及由经过培训的专业小组进行感官分析。结果表明,封瓶类型在瓶内营造了不同的环境,对红葡萄酒的感官属性和化学演变均产生了轻微影响。这些发现凸显了结合多种分析技术以揭示封瓶驱动差异的价值,其中挥发性化合物剖析是最敏感的方法。此外,本研究强调,葡萄酒与封瓶的搭配所调制的差异在储存过程中会变得更加明显,可作为构建葡萄酒身份的酿酒学工具。