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喷洒微水滴会形成发光现象,并在周围气体中引发化学反应。

Spraying of water microdroplets forms luminescence and causes chemical reactions in surrounding gas.

作者信息

Meng Yifan, Xia Yu, Xu Jinheng, Zare Richard N

机构信息

Department of Chemistry, Stanford University, Stanford, CA 94305, USA.

School of Environment and Health, Jianghan University, Wuhan 430056, China.

出版信息

Sci Adv. 2025 Mar 14;11(11):eadt8979. doi: 10.1126/sciadv.adt8979.

Abstract

When neutral water is sprayed, oppositely charged microdroplets are formed. The close approach of oppositely charged microdroplets causes an electrical discharge and leads to luminescent emission. The light emission happens without any external voltage applied, and the electrical discharge is sufficiently energetic to excite, dissociate, or ionize surrounding neutral gas molecules. Thus, sprayed water microdroplets cause chemical reactions to occur. Similar findings to the Urey-Miller experiment were observed by spraying room temperature water microdroplets into a gas mixture containing nitrogen, methane, carbon dioxide, and ammonia, which leads to the synthesis of organic molecules containing carbon-nitrogen (C─N) bonds. These observations provide another explanation for unique reactivity at the gas-water interface, as well as a possible mechanism for making the building blocks of life on early Earth.

摘要

当喷射中性水时,会形成带相反电荷的微滴。带相反电荷的微滴相互靠近会导致放电并产生发光现象。发光过程无需施加任何外部电压,并且放电能量足以激发、解离或电离周围的中性气体分子。因此,喷射出的水微滴会引发化学反应。通过将室温下水微滴喷入含有氮气、甲烷、二氧化碳和氨的气体混合物中,观察到了与尤里 - 米勒实验类似的结果,这导致了含碳 - 氮(C─N)键的有机分子的合成。这些观察结果为气 - 水界面独特的反应性提供了另一种解释,同时也为早期地球上生命基本组成部分的形成提供了一种可能的机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e1a/11908502/7cec4c2c29d1/sciadv.adt8979-f1.jpg

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