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采用废弃生物质棉纤维制备了高性能碳基与水系锌离子混合电容器。

High performance carbon matrix and aqueous zinc ion hybrid capacitors were prepared from waste biomass cotton fiber.

作者信息

Deng Xiaonan, Wu Juan, Wan Lingzhong, Sun Hui, Ni Ying, Zhu Jiabao

机构信息

Institute of Industrial Crops, Anhui Academy of Agricultural Sciences.

Institute of Industrial Crops, Anhui Academy of Agricultural Sciences.

出版信息

Int J Biol Macromol. 2025 May;307(Pt 4):142159. doi: 10.1016/j.ijbiomac.2025.142159. Epub 2025 Mar 17.

DOI:10.1016/j.ijbiomac.2025.142159
PMID:40107538
Abstract

The present study is centered on the development of a novel highly conductive carbon matrix featuring a stable structure and robust functionality, derived from natural biomass. This carbon matrix can be directly employed as an electrode for supercapacitors or serve as a carrier material for electrodes. The modification and activation of natural biomass were executed to prepare tubular carbon nanofibers with porous structures, thereby augmenting the specific surface area, active sites, and permeability of the materials utilized in electrodes. These modifications also guaranteed the electrochemical and structural stability of the electrode materials. For instance, by optimizing the urea dosage and activation temperature while using waste cotton wool as the raw material, we fabricated porous carbon nanofiber materials with a large specific surface area, abundant pore structure, and appropriate nitrogen content. The resulting material demonstrated excellent electrochemical properties such as high specific capacity and good cyclic stability when utilized as a supercapacitor electrode. This synthesis strategy substantiates the feasibility and potential of leveraging biomass waste to produce high-value electrode materials.

摘要

本研究聚焦于开发一种新型的高导电性碳基体,其具有稳定的结构和强大的功能,源自天然生物质。这种碳基体可直接用作超级电容器的电极,或作为电极的载体材料。对天然生物质进行改性和活化以制备具有多孔结构的管状碳纳米纤维,从而增加电极所用材料的比表面积、活性位点和渗透性。这些改性还保证了电极材料的电化学和结构稳定性。例如,以废棉絮为原料,通过优化尿素用量和活化温度,制备出了具有大比表面积、丰富孔结构和适当氮含量的多孔碳纳米纤维材料。所得材料用作超级电容器电极时表现出优异的电化学性能,如高比容量和良好的循环稳定性。这种合成策略证实了利用生物质废料生产高价值电极材料的可行性和潜力。

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