Lee Suwoon, Choi Hansol, Lee Hyunho, Song Hyung-Jun
Department of Safety Engineering, Seoul National University of Science and Technology, Seoul, 01811, South Korea.
Department of Electronic Engineering, Kwangwoon University, Seoul, 01897, South Korea.
Small. 2025 Apr;21(17):e2411539. doi: 10.1002/smll.202411539. Epub 2025 Mar 20.
Recent advances in quantum dot light emitting diode (QLED) technology have enhanced their stability and efficiency. Studies have demonstrated that QLEDs are robust against oxygen, moisture, and low-voltage stress. However, the impact of instantaneous high-voltage exposure on QLEDs, which can occur during manufacturing due to electrostatic discharge (ESD) from friction between non-conductive components, remains unclear. This study systematically investigates the degradation mechanisms of QLEDs caused by ESD at the level of individual layers, pixels, and the overall display panel. When subjected to ESD pulses of several thousand volts for a few nanoseconds, QLEDs exhibit increased leakage current, reduced electroluminescence intensity, and the formation of dark spots within pixels due to the degradation of electrodes rather than the degradation of QDs. Under severe ESD stress (over 10 kV), the electrodes migrate within the device and are finally disconnected. Microstructural analysis confirms that the decreased physical distance between the two electrodes intensified the electric field, potentially converting a diode into a short circuit. The directly exposed pixels are affected by ESD, and those positioned between the ESD source and the ground may also be damaged. These findings underscore the necessity of managing electrostatic accumulation during QLED fabrication to mitigate ESD-related degradation.
量子点发光二极管(QLED)技术的最新进展提高了其稳定性和效率。研究表明,QLED对氧气、水分和低电压应力具有较强的耐受性。然而,由于非导电部件之间的摩擦产生的静电放电(ESD),在制造过程中可能会出现的瞬时高压暴露对QLED的影响仍不清楚。本研究系统地研究了在单个层、像素和整个显示面板层面上,ESD导致QLED退化的机制。当受到几千伏的ESD脉冲作用几纳秒时,QLED会出现漏电流增加、电致发光强度降低,并且由于电极退化而非量子点退化,像素内会形成暗斑。在严重的ESD应力(超过10 kV)下,电极在器件内迁移并最终断开连接。微观结构分析证实,两个电极之间物理距离的减小会增强电场,有可能将二极管转变为短路。直接暴露的像素会受到ESD的影响,位于ESD源和接地之间的像素也可能受损。这些发现强调了在QLED制造过程中管理静电积累以减轻与ESD相关的退化的必要性。