一种带有桥连9,9'-联-9-9-硅芴部分的二硅[2]二茂铁并苯。

A Disila[2]ferrocenophane with a Bridging 9,9'-Bi-9-9-Silafluorene Moiety.

作者信息

Usuba Shinnosuke, Morisako Shogo, Masada Koichiro, Sugamata Koh, Sasamori Takahiro

机构信息

Graduate School of Science and Technology, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba 305-8571, Ibaraki, Japan.

Sagami Chemical Research Institute, Hayakawa 2743-1, Ayase 252-1193, Kanagawa, Japan.

出版信息

Molecules. 2025 Mar 18;30(6):1361. doi: 10.3390/molecules30061361.

DOI:10.3390/molecules30061361

PMID:40142137

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11944698/

Abstract

A disila[2]ferrocenophane bearing a 9,9'-bi-9-9-silafluorene (9-silafluorene dimer) moiety as a bridging unit was synthesized and isolated as a stable crystalline compound. Disila[2]ferrocenophane newly obtained in this study, has been characterized by spectroscopic analyses, single crystal X-ray diffraction (SC-XRD) analysis, and electrochemical measurements. It was found that the obtained disila[2]ferrocenophane was reduced by a reducing agent to generate the corresponding 1,1'-ferrocenediyl-bis(silylanion) via the reductive Si-Si σ-bond cleavage. The trapping reactions of the 1,1'-ferrocenediyl-bis(silylanion) thus generated with electrophiles have also been attempted.

摘要

合成并分离出了一种以9,9'-联-9-9-硅芴（9-硅芴二聚体）部分作为桥连单元的二硅[2]二茂铁并环戊二烯，它是一种稳定的结晶化合物。本研究新得到的二硅[2]二茂铁并环戊二烯已通过光谱分析、单晶X射线衍射（SC-XRD）分析和电化学测量进行了表征。结果发现，所得到的二硅[2]二茂铁并环戊二烯可被还原剂还原，通过Si-Si σ键的还原裂解生成相应的1,1'-二茂铁二基双（硅阴离子）。还尝试了用亲电试剂对由此生成的1,1'-二茂铁二基双（硅阴离子）进行捕获反应。