大环salen稀土配合物的合成及其通过配位球工程调控的骨架转化
Synthesis of macrocyclic salen rare-earth complexes and their framework conversion regulated by coordination sphere engineering.
作者信息
Liu Yi-Fu, Gil-Ramírez Guzmán, Nakamura Takashi
机构信息
Degree Programs in Pure and Applied Sciences, Graduate School of Science and Technology, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan.
School of Chemistry, University of Lincoln, Joseph Banks Laboratories, Lincoln LN6 7DL, UK.
出版信息
Chem Commun (Camb). 2025 Jan 9;61(5):921-924. doi: 10.1039/d4cc03851g.
We now report a macrocyclic rare-earth complex whose frameworks have been regulated between a trimer and a tetramer by an external capping ligand. Coordination sphere engineering of the rare earth metals with flexible and variable coordination numbers (CN > 6) offers a unique way to control the self-assembled structures.
我们现在报道一种大环稀土配合物，其结构框架已通过外部封端配体在三聚体和四聚体之间进行了调控。具有灵活可变配位数（配位数>6）的稀土金属配位球工程提供了一种控制自组装结构的独特方法。
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