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用于碳-硫、碳-硒键形成的磁性纳米催化剂综述

A Comprehensive Review of Magnetic Nanocatalysts for C-S, C-Se Bond Formation.

作者信息

Ali Radwan, Han Jianlin, Kazemi Mosstafa, Javahershenas Ramin

机构信息

Al-Qadisiyah University, College of Dentistry, Department of Basic Sciences, Qadisiyyah, Iraq.

Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China.

出版信息

ChemistryOpen. 2025 Sep;14(9):e202500041. doi: 10.1002/open.202500041. Epub 2025 Mar 27.

DOI:10.1002/open.202500041
PMID:40145843
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12409848/
Abstract

This review manuscript examines magnetic nanocatalysts and their pivotal role in forming carbon-sulfur (C-S) and carbon-selenium (C-Se) bonds. The study delves into the latest advancements in the synthesis, characterization, and application of magnetic nanocatalysts, highlighting their unique advantages, including enhanced catalytic activity, superior selectivity, and easy recovery through magnetic separation, which align with the principles of green chemistry. Through a critical analysis of recent research findings, this review also explores the mechanistic pathways facilitated by these nanocatalysts, offering insights into their operational efficiency and potential for recyclability. The manuscript aims not only to catalog the current achievements in this burgeoning field but also to identify challenges and propose future directions for developing more efficient, sustainable, and versatile catalytic systems for C-S and C-Se bond formation. By encompassing a broad spectrum of magnetic nanocatalysts, ranging from bare magnets to functionalized and composite materials, this review is a comprehensive resource for researchers engaged in organic synthesis, catalysis, and sustainable chemistry.

摘要

这篇综述手稿探讨了磁性纳米催化剂及其在形成碳 - 硫（C - S）键和碳 - 硒（C - Se）键方面的关键作用。该研究深入探讨了磁性纳米催化剂在合成、表征和应用方面的最新进展，强调了它们的独特优势，包括增强的催化活性、卓越的选择性以及通过磁分离易于回收，这些优势符合绿色化学的原则。通过对近期研究结果的批判性分析，本综述还探索了这些纳米催化剂促进的反应机理途径，深入了解它们的运行效率和可回收潜力。该手稿不仅旨在梳理这一新兴领域的当前成就，还旨在识别挑战并为开发更高效、可持续和多功能的用于C - S和C - Se键形成的催化体系提出未来方向。通过涵盖从裸磁体到功能化和复合材料等广泛的磁性纳米催化剂，本综述为从事有机合成、催化和可持续化学研究的人员提供了全面的资源。

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