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用于废水处理的由玉米芯衍生的碳量子点/ZnFeO/氧化石墨烯的稳健三元体系。

Robust ternary system of corncob-derived carbon quantum dots/ ZnFeO/graphene oxide for wastewater treatment.

作者信息

Qayyum Wajeeha, Tahir Noor, Zahid Muhammad, Noreen Saima, Yaseen Muhammad, AlObaid Abeer A, Abbas Qamar, Mustafa Ghulam

机构信息

Department of Chemistry, University of Agriculture, Faisalabad, 38040, Pakistan.

Department of Physics, University of Agriculture, Faisalabad, Pakistan.

出版信息

BMC Chem. 2025 Apr 2;19(1):86. doi: 10.1186/s13065-025-01462-w.

Abstract

Water contamination emerging from urban and industrial waste disposal is posing an alarming threat to human and marine life. Hence, it is imperative to take a crucial approach to lowering the overall cost and time of wastewater treatment. The efficiency of heterogeneous photo Fenton green wastewater treatment processes relies mainly on the morphology and surface interface properties of photocatalysts for harnessing maximum sunlight energy. This research work reports for the first time the hydrothermal synthesis of ternary zinc ferrite coupled with carbon quantum dots derived primarily from corncob biomass and supported over graphene oxide. The physiochemical properties and microstructure of magnetic graphene oxide anchored over carbon quantum dots included Fourier Transform Infrared Spectroscopy, Scanning Electron Microscope/Energy Dispersive X-ray, X-ray photoelectron spectroscopy, X-ray diffraction and Ultraviolet-Visible Spectroscopy. The effect of several factors on the photocatalytic degradation of Rhodamine B (RhB) dye was studied and maximum degradation was attained at optimized conditions of pH = 4, catalyst concentration (20 mg/100 mL), oxidant dose (10 mM) and degradation time (60 min). Response surface methodology was used to determine the optimization of various interacting parameters. The current research focused on the utilization of waste corncob biomass as a potential candidate for the novel ternary nanocomposite for effective treatment dye wastewater and reuse of treated dye water over wheat seeds germination.

摘要

城市和工业废物处理产生的水污染正给人类和海洋生物带来惊人的威胁。因此,采取关键方法降低废水处理的总体成本和时间势在必行。多相光芬顿绿色废水处理工艺的效率主要取决于光催化剂的形态和表面界面性质,以充分利用最大的太阳能。本研究首次报道了主要由玉米芯生物质衍生并负载在氧化石墨烯上的三元铁酸锌与碳量子点的水热合成。负载在碳量子点上的磁性氧化石墨烯的物理化学性质和微观结构包括傅里叶变换红外光谱、扫描电子显微镜/能量色散X射线、X射线光电子能谱、X射线衍射和紫外可见光谱。研究了几个因素对罗丹明B(RhB)染料光催化降解的影响,在pH = 4、催化剂浓度(20 mg/100 mL)、氧化剂剂量(10 mM)和降解时间(60分钟)的优化条件下实现了最大降解。采用响应面法确定各种相互作用参数的优化。当前的研究集中在利用废弃玉米芯生物质作为新型三元纳米复合材料的潜在候选物,用于有效处理染料废水以及处理后的染料水在小麦种子萌发上的再利用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b0d/11967066/1f71872201ef/13065_2025_1462_Fig1_HTML.jpg

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