Zhang Zijun, Yan Wenda, Sun Huadong, Ding Yongling, Dong Fuqiang
Shandong High-Speed Construction Management Group Co.,Ltd, Shandong Province, Jinan, 250000, China.
Shandong Provincial Department of Finance, Shandong Province, Jinan, 250002, China.
Sci Rep. 2025 Apr 3;15(1):11393. doi: 10.1038/s41598-025-91868-2.
Dry modified Styrene-Butadiene-Styrene is an innovative asphalt modification method applied at the mixture level, offering many advantages in environmental-friendliness, efficiency, and convenience. However, its engineering application lacks comprehensive theoretical support. To address this gap and provide practical guidance for the production process of dry modified Styrene-Butadiene-Styrene asphalt mixtures, this study evaluates systematically the mixing conditions and investigates the microscopic mechanisms and performance impacts of dry modified Styrene-Butadiene-Styrene concerning modifier dosage, mixing temperature, mixing duration, and storage time. The research includes multiple scales: molecular simulations to analyze microscopic interactions, fluorescence microscopy and Fourier-transform infrared spectroscopy for mesoscopic observations, and asphalt mixture performance tests for macroscopic evaluations. Molecular dynamics simulation results indicate that when the dosage of dry modified SBS increases from 4 to 6%, the diffusivity improves by 20% and the interface strength increases by 32%. Microscopic tests results show that the optimal diffusion effect of SBS can be achieved when the mixing time of the mixture is 90 s. Macroscopic experiments provide the best preparation scheme for dry modified SBS: SBS dosage of 6%, mixing temperature of 180-185 °C, mixing time of 90 s, and storage time of 30 min. Under these conditions, the pavement performance of the dry modified SBS mixture can achieve optimal results.
干法改性苯乙烯-丁二烯-苯乙烯(SBS)是一种在混合料层面应用的创新型沥青改性方法,在环保、效率和便利性方面具有诸多优势。然而,其工程应用缺乏全面的理论支持。为填补这一空白并为干法改性SBS沥青混合料的生产过程提供实际指导,本研究系统评估了拌合条件,并研究了干法改性SBS在改性剂用量、拌合温度、拌合时间和储存时间方面的微观机理及性能影响。该研究涵盖多个尺度:通过分子模拟分析微观相互作用,利用荧光显微镜和傅里叶变换红外光谱进行细观观测,并通过沥青混合料性能试验进行宏观评价。分子动力学模拟结果表明,当干法改性SBS的用量从4%增加到6%时,扩散率提高20%,界面强度增加32%。微观试验结果表明,当混合料的拌合时间为90秒时,SBS可实现最佳扩散效果。宏观试验给出了干法改性SBS的最佳制备方案:SBS用量6%,拌合温度180 - 185°C,拌合时间90秒,储存时间30分钟。在这些条件下,干法改性SBS混合料的路用性能可达到最佳效果。