Suppr超能文献

用于丙酮气体传感及光催化降解甲基橙的新型双功能锡酸锰薄膜

Novel dual-functional manganese stannate thin film for acetone gas sensing and photocatalytic methyl orange degradation.

作者信息

Kompa Akshayakumar, Kekuda Dhananjaya, Murari M S, Rao K Mohan

机构信息

Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education Manipal 576 104 India

Department of Engineering Science and Humanities, Thakur College of Engineering and Technology Mumbai 400101 India.

出版信息

RSC Adv. 2025 Apr 4;15(13):10460-10472. doi: 10.1039/d4ra08391a. eCollection 2025 Mar 28.

Abstract

Increasing health concerns due to pollution has led to the development of various materials to control exposure to pollutants such as toxic gases and contaminated water. In this study, novel manganese stannate (MTO) composite thin films were synthesized sol-gel spin coating and their structural, morphological, and chemical properties were extensively characterized. In addition, their photocatalytic and gas-sensing abilities were evaluated. In photocatalysis, degradation efficiency measures of how well a photocatalyst can degrade pollutants or dyes under light exposure. Remarkably, the MTO film exhibited a high degradation efficiency of 67% for methyl orange (MO) dye when exposed to UV light for 150 minutes. We also examined the gas-sensing properties of the MTO thin films, particularly their response to acetone. In gas sensors, sensitivity is often reported as a percentage, indicating the relative change in the sensor's response per unit change in analyte concentration. Herein, the sensors displayed a linear response within the 1-9 ppm range of acetone concentration at an operating temperature of 200 °C. They also exhibited excellent selectivity, sensitivity, and repeatability, thus emerging as promising candidates for acetone gas-sensing applications. A sensitivity of 22% was achieved by the sensors, allowing for a low detection limit of 1 ppm, which indicated their high sensitivity towards acetone gas. Moreover, the MTO sensor exhibited response and recovery times of 15 and 16 seconds, respectively. Based on these results, the MTO thin film is a potential material for photocatalytic MO degradation and a gas sensor for acetone detection.

摘要

由于污染导致的健康问题日益受到关注,这促使人们开发各种材料来控制对有毒气体和受污染水等污染物的接触。在本研究中,通过溶胶 - 凝胶旋涂法合成了新型锰锡酸盐(MTO)复合薄膜,并对其结构、形态和化学性质进行了广泛表征。此外,还评估了它们的光催化和气体传感能力。在光催化中,降解效率衡量的是光催化剂在光照下分解污染物或染料的能力。值得注意的是,MTO薄膜在紫外光照射150分钟时,对甲基橙(MO)染料的降解效率高达67%。我们还研究了MTO薄膜的气敏特性,特别是它们对丙酮的响应。在气体传感器中,灵敏度通常以百分比表示,表明传感器响应随分析物浓度单位变化的相对变化。在此,传感器在200°C的工作温度下,在1 - 9 ppm的丙酮浓度范围内呈现线性响应。它们还表现出优异的选择性、灵敏度和重复性,因此成为丙酮气体传感应用的有前途的候选材料。传感器的灵敏度达到22%,检测下限低至1 ppm,这表明它们对丙酮气体具有高灵敏度。此外,MTO传感器的响应时间和恢复时间分别为15秒和16秒。基于这些结果,MTO薄膜是用于光催化降解MO的潜在材料和用于检测丙酮的气体传感器。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b36/11969144/22bd8d7e0fdd/d4ra08391a-f1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验