Preparation of Polypyrrole/Montmorillonite/Polypropylene Composite Membranes and Investigation of Their Adsorption Performance for Methyl Orange and Pb.

This study investigates the efficient and recyclable use of polymer-based membrane materials in wastewater treatment, focusing on calcium-based montmorillonite (Ca-MMT), pyrrole (Py), and polypropylene (PP). Through sodium activation, organic modification, pyrrole intercalation, and in situ polymerization, polypyrrole/montmorillonite (PPy/MMT) was synthesized. A polypyrrole/montmorillonite/polypropylene composite membrane (PPy/MMT/PP) was then fabricated using melt compression and coating techniques for pollutant adsorption. The modification of montmorillonite by PPy was examined, alongside the morphology, composition, and structure of PPy/MMT/PP. The membrane's adsorption performance for methyl orange and Pb⁺ was evaluated, with a focus on cyclic adsorption. The results showed that PPy increased the interlayer spacing of montmorillonite from 1.23 nm to 1.74 nm and enhanced its specific surface area by 99.424 m/g. The composite membrane exhibited improved wettability and adsorption capacity, achieving removal rates of 95.98% for methyl orange and 88.48% for Pb⁺, following pseudo-second-order kinetics. The membrane demonstrated recyclability, maintaining efficient adsorption/desorption over three cycles. This work provides valuable insights and technical support for sustainable wastewater treatment using polymer-based membranes.