Ventosinos Louzao Vanessa, García Murias Denise, De Dios Álvarez Miguel Ángel, Acuña Domínguez Pablo Alberto, Paredes Barros Esteban, Ledo Bañobre Raquel
Materials Innovation Area, CTAG - Automotive Technology Centre of Galicia, O Porriño, Pontevedra, 36475, Spain.
Open Res Eur. 2025 Sep 9;4:51. doi: 10.12688/openreseurope.16888.4. eCollection 2024.
This research focuses on the study of the tensile modulus and impact resistance of acrylonitrile-butadiene-styrene (ABS) and its blends with polycarbonate (ABS/PC) including recycled and painted material. A comprehensive assessment was done to determine the impact of reprocessing cycles, remaining coating and their combined effect in the final properties of the recycled polymer. Post-consumer materials are in an already-aged state, lowering their initial properties. Mechanical recycling methods showed that the reprocessing cycles have a higher impact on the mechanical performance than the amount of recycling material content. Also, the material is often coated when they are about to be recycled. The remaining coating impurities play a major role in the recycling process, losing up to 42% of the impact resistance for ABS and 28% for ABS/PC. It was demonstrated that below a 10% of remaining paint, both materials retained is performance as a neat product. Impurities was declared to be the most pernicious element on the recycling process and their elimination must be a priority regarding this objective. These results provide a better knowledge of the recycling effect and can be used to decide the potential recyclability of plastic. The ascribed project of this study (DECOAT) aims to develop efficient systems to remove coatings at the end-of-life of the part, to reduce the damage and promote the use of recycled material in high-tech applications.
本研究聚焦于丙烯腈-丁二烯-苯乙烯共聚物(ABS)及其与聚碳酸酯的共混物(ABS/PC)(包括回收材料和涂漆材料)的拉伸模量和抗冲击性研究。进行了全面评估,以确定再加工循环次数、残留涂层及其综合作用对回收聚合物最终性能的影响。消费后材料已处于老化状态,其初始性能有所降低。机械回收方法表明,再加工循环次数对机械性能的影响比回收材料的含量更大。此外,材料在即将回收时通常已被涂覆。残留的涂层杂质在回收过程中起主要作用,ABS的抗冲击性损失高达42%,ABS/PC的抗冲击性损失高达28%。结果表明,当残留涂料低于10%时,两种材料都能保持其作为纯产品的性能。杂质被认为是回收过程中最有害的因素,消除杂质必须是实现这一目标的首要任务。这些结果有助于更好地了解回收效果,并可用于判断塑料的潜在可回收性。本研究的相关项目(DECOAT)旨在开发高效系统,在部件使用寿命结束时去除涂层,减少损害,并促进回收材料在高科技应用中的使用。