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基于石墨烯的聚合物涂层浸渍以提高耐腐蚀性。

Graphene-Based Impregnation into Polymeric Coating for Corrosion Resistance.

作者信息

Yadav Arti, Panjikar Santosh, Singh Raman R K

机构信息

Department of Chemical and Biological Engineering, Monash University, Melbourne, VIC 3800, Australia.

Australian Nuclear Science and Technology Organisation, Australian Synchrotron, 800 Blackburn Road, Clayton, Melbourne, VIC 3168, Australia.

出版信息

Nanomaterials (Basel). 2025 Mar 24;15(7):486. doi: 10.3390/nano15070486.

Abstract

This review explores the development and application of the impregnation of graphene-based materials into polymeric coatings to enhance corrosion resistance. Derivatives of graphene, such as graphene oxide (GO) and reduced graphene oxide (rGO), have been increasingly integrated into polymer matrices to enhance polymers' mechanical, thermal, and barrier properties. Various synthesis approaches, viz., electrochemical deposition, chemical reduction, and the incorporation of functionalised graphene derivatives, have been explored for improving the dispersion and stability of graphene within polymers. These graphene-impregnated coatings have shown promising results in improving corrosion resistance by enhancing impermeability to corrosive agents and reinforcing mechanical strength under corrosive conditions. While the addition of graphene notably enhances coating performance, challenges remain in achieving uniform graphene dispersion and addressing the trade-offs between thickness and flexibility. This review highlights current advancements, limitations, and future directions, with a particular emphasis on optimising the synthesis techniques to maximise corrosion resistance while maintaining coating durability and economic feasibility.

摘要

本综述探讨了将基于石墨烯的材料浸渍到聚合物涂层中以提高耐腐蚀性的发展与应用。石墨烯的衍生物,如氧化石墨烯(GO)和还原氧化石墨烯(rGO),已越来越多地融入聚合物基体中,以增强聚合物的机械、热和阻隔性能。为了改善石墨烯在聚合物中的分散性和稳定性,人们探索了各种合成方法,即电化学沉积、化学还原以及引入功能化石墨烯衍生物。这些含石墨烯的涂层在提高耐腐蚀性方面显示出了有前景的结果,通过增强对腐蚀剂的不渗透性以及在腐蚀条件下增强机械强度来实现。虽然添加石墨烯显著提高了涂层性能,但在实现石墨烯的均匀分散以及解决厚度与柔韧性之间的权衡方面仍存在挑战。本综述突出了当前的进展、局限性和未来方向,特别强调优化合成技术,以在保持涂层耐久性和经济可行性的同时最大化耐腐蚀性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b46/11990139/708fdfb9e8d1/nanomaterials-15-00486-g001.jpg

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